Preparation of a bio-based epoxy with comparable properties to those of petroleum-based counterparts

In this paper a bio-based epoxy with outstanding thermal and mechanical properties was synthesized using a rosin-based epoxy monomer and a rosin-based curing agent. The chemical structures of rosin based epoxy monomer and curing agent were confirmed by Nuclear Magnetic Resonance (NMR) and Fourier Tr...

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Main Authors: X. Q. Liu, W. Huang, Y. H. Jiang, J. Zhu, C. Z. Zhang
Format: Article
Language:English
Published: Budapest University of Technology and Economics 2012-04-01
Series:eXPRESS Polymer Letters
Subjects:
Online Access:http://www.expresspolymlett.com/letolt.php?file=EPL-0002948&mi=cd
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author X. Q. Liu
W. Huang
Y. H. Jiang
J. Zhu
C. Z. Zhang
author_facet X. Q. Liu
W. Huang
Y. H. Jiang
J. Zhu
C. Z. Zhang
author_sort X. Q. Liu
collection DOAJ
description In this paper a bio-based epoxy with outstanding thermal and mechanical properties was synthesized using a rosin-based epoxy monomer and a rosin-based curing agent. The chemical structures of rosin based epoxy monomer and curing agent were confirmed by Nuclear Magnetic Resonance (NMR) and Fourier Transform Infrared (FT-IR) spectra. The flexural mechanical and dynamic mechanical properties as well as thermal stability of the cured epoxy were investigated. The results showed that the cured epoxy exhibited a glass transition temperature (Tg) of 164°C and its flexural strength and modulus were as high as 70 and 2200 MPa, respectively. This indicated that a wholly bio-based epoxy resin possessing high performance was successfully obtained.
format Article
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institution Matheson Library
issn 1788-618X
language English
publishDate 2012-04-01
publisher Budapest University of Technology and Economics
record_format Article
series eXPRESS Polymer Letters
spelling doaj-art-5997e4b5982b4bccb9a06db5a3db1ea52025-08-02T08:38:09ZengBudapest University of Technology and EconomicseXPRESS Polymer Letters1788-618X2012-04-016429329810.3144/expresspolymlett.2012.32Preparation of a bio-based epoxy with comparable properties to those of petroleum-based counterpartsX. Q. LiuW. HuangY. H. JiangJ. ZhuC. Z. ZhangIn this paper a bio-based epoxy with outstanding thermal and mechanical properties was synthesized using a rosin-based epoxy monomer and a rosin-based curing agent. The chemical structures of rosin based epoxy monomer and curing agent were confirmed by Nuclear Magnetic Resonance (NMR) and Fourier Transform Infrared (FT-IR) spectra. The flexural mechanical and dynamic mechanical properties as well as thermal stability of the cured epoxy were investigated. The results showed that the cured epoxy exhibited a glass transition temperature (Tg) of 164°C and its flexural strength and modulus were as high as 70 and 2200 MPa, respectively. This indicated that a wholly bio-based epoxy resin possessing high performance was successfully obtained.http://www.expresspolymlett.com/letolt.php?file=EPL-0002948&mi=cdBiopolymers, biocompositesrosinthermosetting resinbio-based
spellingShingle X. Q. Liu
W. Huang
Y. H. Jiang
J. Zhu
C. Z. Zhang
Preparation of a bio-based epoxy with comparable properties to those of petroleum-based counterparts
eXPRESS Polymer Letters
Biopolymers, biocomposites
rosin
thermosetting resin
bio-based
title Preparation of a bio-based epoxy with comparable properties to those of petroleum-based counterparts
title_full Preparation of a bio-based epoxy with comparable properties to those of petroleum-based counterparts
title_fullStr Preparation of a bio-based epoxy with comparable properties to those of petroleum-based counterparts
title_full_unstemmed Preparation of a bio-based epoxy with comparable properties to those of petroleum-based counterparts
title_short Preparation of a bio-based epoxy with comparable properties to those of petroleum-based counterparts
title_sort preparation of a bio based epoxy with comparable properties to those of petroleum based counterparts
topic Biopolymers, biocomposites
rosin
thermosetting resin
bio-based
url http://www.expresspolymlett.com/letolt.php?file=EPL-0002948&mi=cd
work_keys_str_mv AT xqliu preparationofabiobasedepoxywithcomparablepropertiestothoseofpetroleumbasedcounterparts
AT whuang preparationofabiobasedepoxywithcomparablepropertiestothoseofpetroleumbasedcounterparts
AT yhjiang preparationofabiobasedepoxywithcomparablepropertiestothoseofpetroleumbasedcounterparts
AT jzhu preparationofabiobasedepoxywithcomparablepropertiestothoseofpetroleumbasedcounterparts
AT czzhang preparationofabiobasedepoxywithcomparablepropertiestothoseofpetroleumbasedcounterparts