Effects of Aggregate-to-Binder Ratio on Mechanical Performance of Engineered Geopolymer Composites with Recycled Rubber Aggregates

This study investigates the development of a fully rubberized fine-aggregate engineered geopolymer composite (R-EGC) by replacing quartz sand with waste rubber particles (RPs). The influence of the rubber aggregate-to-binder mass ratio (A/B) on the performance of the R-EGC was systematically examine...

Full description

Saved in:
Bibliographic Details
Main Authors: Yiwei Li, Shuzhuo Zhi, Ran Chai, Zhiying Zhou, Jiarui He, Zizhao Yao, Zhan Yang, Genquan Zhong, Yongchang Guo
Format: Article
Language:English
Published: MDPI AG 2025-07-01
Series:Buildings
Subjects:
Online Access:https://www.mdpi.com/2075-5309/15/14/2496
Tags: Add Tag
No Tags, Be the first to tag this record!
_version_ 1839616291884761088
author Yiwei Li
Shuzhuo Zhi
Ran Chai
Zhiying Zhou
Jiarui He
Zizhao Yao
Zhan Yang
Genquan Zhong
Yongchang Guo
author_facet Yiwei Li
Shuzhuo Zhi
Ran Chai
Zhiying Zhou
Jiarui He
Zizhao Yao
Zhan Yang
Genquan Zhong
Yongchang Guo
author_sort Yiwei Li
collection DOAJ
description This study investigates the development of a fully rubberized fine-aggregate engineered geopolymer composite (R-EGC) by replacing quartz sand with waste rubber particles (RPs). The influence of the rubber aggregate-to-binder mass ratio (A/B) on the performance of the R-EGC was systematically examined from both macroscopic and microscopic perspectives. Quantitative analysis of crack width and number was conducted using binarized image-processing techniques to elucidate the crack propagation patterns. Moreover, scanning electron microscopy (SEM) and energy-dispersive spectroscopy (EDS) were employed to analyze the interfacial transition zone (ITZ) between the rubber aggregates and the geopolymer matrix under varying A/B ratios, aiming to explore the underlying failure mechanisms of the R-EGC. The research results indicated that the flowability of the R-EGC decreased gradually with increasing A/B ratio. The flowability of R-0.1 was 73.5%, outperforming R-0.2 and R-0.3 (66% and 65%, respectively). R-0.1 achieved the highest compressive strength of 35.3 MPa (compared to 31.2 MPa and 28.4 MPa for R-0.2 and R-0.3, respectively). R-0.3 demonstrated the most effective crack-control capability, with a tensile strength of 3.96 MPa (representing increases of 11.9% and 3.7% compared to R-0.1 and R-0.2, respectively) and the smallest crack width of 104 μm (indicating reductions of 20.6% and 43.5% compared to R-0.1 and R-0.2, respectively). R-0.2 exhibited the best ductility, with an ultimate tensile strain of 8.33%. Microstructural tests revealed that the interfacial transition zone (ITZ) widths for R-0.1, R-0.2, and R-0.3 were 2.47 μm, 4.53 μm, and 1.09 μm, respectively. An appropriate increase in the ITZ width was found to be beneficial for enhancing tensile ductility, but it compromised the crack-control ability of the R-EGC, thereby reducing its durability. Overall, this study clarifies the fundamental influence of the A/B ratio on the mechanical performance of the R-EGC. The findings provide valuable insights for future research in this field.
format Article
id doaj-art-2a8c7ab3d2f94e20929dba3f14b2f89f
institution Matheson Library
issn 2075-5309
language English
publishDate 2025-07-01
publisher MDPI AG
record_format Article
series Buildings
spelling doaj-art-2a8c7ab3d2f94e20929dba3f14b2f89f2025-07-25T13:17:30ZengMDPI AGBuildings2075-53092025-07-011514249610.3390/buildings15142496Effects of Aggregate-to-Binder Ratio on Mechanical Performance of Engineered Geopolymer Composites with Recycled Rubber AggregatesYiwei Li0Shuzhuo Zhi1Ran Chai2Zhiying Zhou3Jiarui He4Zizhao Yao5Zhan Yang6Genquan Zhong7Yongchang Guo8School of Civil and Transportation Engineering, Guangdong University of Technology, Guangzhou 510006, ChinaSchool of Civil and Transportation Engineering, Guangdong University of Technology, Guangzhou 510006, ChinaSchool of Civil and Transportation Engineering, Guangdong University of Technology, Guangzhou 510006, ChinaSchool of Civil and Transportation Engineering, Guangdong University of Technology, Guangzhou 510006, ChinaSchool of Civil and Transportation Engineering, Guangdong University of Technology, Guangzhou 510006, ChinaSchool of Civil and Transportation Engineering, Guangdong University of Technology, Guangzhou 510006, ChinaGuangzhou Building Materials Institute Limited Company, Guangzhou 510663, ChinaSchool of Civil and Transportation Engineering, Guangdong University of Technology, Guangzhou 510006, ChinaSchool of Civil and Transportation Engineering, Guangdong University of Technology, Guangzhou 510006, ChinaThis study investigates the development of a fully rubberized fine-aggregate engineered geopolymer composite (R-EGC) by replacing quartz sand with waste rubber particles (RPs). The influence of the rubber aggregate-to-binder mass ratio (A/B) on the performance of the R-EGC was systematically examined from both macroscopic and microscopic perspectives. Quantitative analysis of crack width and number was conducted using binarized image-processing techniques to elucidate the crack propagation patterns. Moreover, scanning electron microscopy (SEM) and energy-dispersive spectroscopy (EDS) were employed to analyze the interfacial transition zone (ITZ) between the rubber aggregates and the geopolymer matrix under varying A/B ratios, aiming to explore the underlying failure mechanisms of the R-EGC. The research results indicated that the flowability of the R-EGC decreased gradually with increasing A/B ratio. The flowability of R-0.1 was 73.5%, outperforming R-0.2 and R-0.3 (66% and 65%, respectively). R-0.1 achieved the highest compressive strength of 35.3 MPa (compared to 31.2 MPa and 28.4 MPa for R-0.2 and R-0.3, respectively). R-0.3 demonstrated the most effective crack-control capability, with a tensile strength of 3.96 MPa (representing increases of 11.9% and 3.7% compared to R-0.1 and R-0.2, respectively) and the smallest crack width of 104 μm (indicating reductions of 20.6% and 43.5% compared to R-0.1 and R-0.2, respectively). R-0.2 exhibited the best ductility, with an ultimate tensile strain of 8.33%. Microstructural tests revealed that the interfacial transition zone (ITZ) widths for R-0.1, R-0.2, and R-0.3 were 2.47 μm, 4.53 μm, and 1.09 μm, respectively. An appropriate increase in the ITZ width was found to be beneficial for enhancing tensile ductility, but it compromised the crack-control ability of the R-EGC, thereby reducing its durability. Overall, this study clarifies the fundamental influence of the A/B ratio on the mechanical performance of the R-EGC. The findings provide valuable insights for future research in this field.https://www.mdpi.com/2075-5309/15/14/2496rubber particles (RPs)aggregate-to-binder ratiosengineered geopolymer composites (EGCs)interfacial transition zone (ITZ)axial compressive behavioraxial tensile behavior
spellingShingle Yiwei Li
Shuzhuo Zhi
Ran Chai
Zhiying Zhou
Jiarui He
Zizhao Yao
Zhan Yang
Genquan Zhong
Yongchang Guo
Effects of Aggregate-to-Binder Ratio on Mechanical Performance of Engineered Geopolymer Composites with Recycled Rubber Aggregates
Buildings
rubber particles (RPs)
aggregate-to-binder ratios
engineered geopolymer composites (EGCs)
interfacial transition zone (ITZ)
axial compressive behavior
axial tensile behavior
title Effects of Aggregate-to-Binder Ratio on Mechanical Performance of Engineered Geopolymer Composites with Recycled Rubber Aggregates
title_full Effects of Aggregate-to-Binder Ratio on Mechanical Performance of Engineered Geopolymer Composites with Recycled Rubber Aggregates
title_fullStr Effects of Aggregate-to-Binder Ratio on Mechanical Performance of Engineered Geopolymer Composites with Recycled Rubber Aggregates
title_full_unstemmed Effects of Aggregate-to-Binder Ratio on Mechanical Performance of Engineered Geopolymer Composites with Recycled Rubber Aggregates
title_short Effects of Aggregate-to-Binder Ratio on Mechanical Performance of Engineered Geopolymer Composites with Recycled Rubber Aggregates
title_sort effects of aggregate to binder ratio on mechanical performance of engineered geopolymer composites with recycled rubber aggregates
topic rubber particles (RPs)
aggregate-to-binder ratios
engineered geopolymer composites (EGCs)
interfacial transition zone (ITZ)
axial compressive behavior
axial tensile behavior
url https://www.mdpi.com/2075-5309/15/14/2496
work_keys_str_mv AT yiweili effectsofaggregatetobinderratioonmechanicalperformanceofengineeredgeopolymercompositeswithrecycledrubberaggregates
AT shuzhuozhi effectsofaggregatetobinderratioonmechanicalperformanceofengineeredgeopolymercompositeswithrecycledrubberaggregates
AT ranchai effectsofaggregatetobinderratioonmechanicalperformanceofengineeredgeopolymercompositeswithrecycledrubberaggregates
AT zhiyingzhou effectsofaggregatetobinderratioonmechanicalperformanceofengineeredgeopolymercompositeswithrecycledrubberaggregates
AT jiaruihe effectsofaggregatetobinderratioonmechanicalperformanceofengineeredgeopolymercompositeswithrecycledrubberaggregates
AT zizhaoyao effectsofaggregatetobinderratioonmechanicalperformanceofengineeredgeopolymercompositeswithrecycledrubberaggregates
AT zhanyang effectsofaggregatetobinderratioonmechanicalperformanceofengineeredgeopolymercompositeswithrecycledrubberaggregates
AT genquanzhong effectsofaggregatetobinderratioonmechanicalperformanceofengineeredgeopolymercompositeswithrecycledrubberaggregates
AT yongchangguo effectsofaggregatetobinderratioonmechanicalperformanceofengineeredgeopolymercompositeswithrecycledrubberaggregates