Thermal Strain and Microstrain in a Polymorphic Schiff Base: Routes to Thermosalience

Thermal Strain and Microstrain in a Polymorphic Schiff Base: Routes to Thermosalience

We present a comprehensive structural and thermomechanical investigation of <i>N</i>-salicylideneaniline, a Schiff base derivative that exhibits remarkable thermosalient phase transition behavior. By combining variable-temperature X-ray powder diffraction (VT-XRPD), differential scanning...

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Bibliographic Details
Main Authors: Teodoro Klaser, Marko Jaklin, Jasminka Popović, Ivan Grgičević, Željko Skoko
Format: Article
Language:English
Published: MDPI AG 2025-06-01
Series:Molecules
Subjects:
thermomechanical actuation
negative thermal expansion (NTE)
variable-temperature X-ray powder diffraction (VT-XRPD)
principal axis strain analysis
polymorphic transition dynamics
crystallographic stress anisotropy
Online Access:https://www.mdpi.com/1420-3049/30/12/2567
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