Mechanochemical Synthesis of Potassium–Ion Conductor K3SbS4
Antimony-based sulfide solid electrolytes exhibit high conductivity for alkaline cations. In this study, we synthesized K3SbS4 potassium-ion conductors using the mechanochemical method for the nominal compositions with x mol% excess K2S (x = 0, 5, 10, and 15) to compensate for the chemical impuritie...
Saved in:
| Main Authors: | , , , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
The Electrochemical Society of Japan
2025-07-01
|
| Series: | Electrochemistry |
| Subjects: | |
| Online Access: | https://www.jstage.jst.go.jp/article/electrochemistry/93/7/93_25-00082/_html/-char/en |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| Summary: | Antimony-based sulfide solid electrolytes exhibit high conductivity for alkaline cations. In this study, we synthesized K3SbS4 potassium-ion conductors using the mechanochemical method for the nominal compositions with x mol% excess K2S (x = 0, 5, 10, and 15) to compensate for the chemical impurities in the K2S reagent. The mechanochemically prepared samples showed X-ray diffraction patterns similar to β-K3SbS4 in all the compositions. Raman bands attributed to the SbS43− unit were observed in all the samples. The ionic conductivities at 25 °C showed a positive correlation with increasing x, reaching a maximum ionic conductivity of 3.6 × 10−6 S cm−1 at 10 mol% excess K2S. Subsequent heat-treatment further enhanced the ionic conductivity, achieving 1.2 × 10−5 S cm−1 at 25 °C. This improvement is attributed to the nominal composition being close to that of K3SbS4 by adjusting the excess amount of K2S and the increased crystallinity of β-K3SbS4. |
|---|---|
| ISSN: | 2186-2451 |