Natural rubber/graphene oxide composites: Effect of sheet size on mechanical properties and strain-induced crystallization behavior

In order to analyze the influence of the lateral size of graphene oxide (GO) on the properties of natural rubber/graphene oxide (NR/GO) nanocomposites, three different sized graphene oxide sheets, namely G1, G2 and G3 were used to fabricate a series of NR/GO nanocomposites by latex mixing. The resul...

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Main Authors: X. Wu, T. F. Lin, Z. H. Tang, B. C. Guo, G. S. Huang
Format: Article
Language:English
Published: Budapest University of Technology and Economics 2015-08-01
Series:eXPRESS Polymer Letters
Subjects:
Online Access:http://www.expresspolymlett.com/letolt.php?file=EPL-0005915&mi=cd
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author X. Wu
T. F. Lin
Z. H. Tang
B. C. Guo
G. S. Huang
author_facet X. Wu
T. F. Lin
Z. H. Tang
B. C. Guo
G. S. Huang
author_sort X. Wu
collection DOAJ
description In order to analyze the influence of the lateral size of graphene oxide (GO) on the properties of natural rubber/graphene oxide (NR/GO) nanocomposites, three different sized graphene oxide sheets, namely G1, G2 and G3 were used to fabricate a series of NR/GO nanocomposites by latex mixing. The results indicate that adding GO can remarkably increase the modulus of NR. The enhancement of modulus is strongly dependent on the size of GO sheets incorporated. G1 with smallest sheet size gives the maximum reinforcement effect compared with G2 and G3. Dynamic mechanical measurement and swelling ratios (Qf/Qg) indicate that G1 has stronger interfacial interaction with NR. XRD shows G1 is more effective in accelerating the strain-induced crystallization (SIC) of NR. The strong interfacial interaction facilitates the stress transfer and strain-induced crystallization, both of which lead to the improved modulus.
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publisher Budapest University of Technology and Economics
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series eXPRESS Polymer Letters
spelling doaj-art-f427cc55d19e4830903b02d38d2bf0aa2025-08-02T23:26:41ZengBudapest University of Technology and EconomicseXPRESS Polymer Letters1788-618X2015-08-019867268510.3144/expresspolymlett.2015.63Natural rubber/graphene oxide composites: Effect of sheet size on mechanical properties and strain-induced crystallization behaviorX. WuT. F. LinZ. H. TangB. C. GuoG. S. HuangIn order to analyze the influence of the lateral size of graphene oxide (GO) on the properties of natural rubber/graphene oxide (NR/GO) nanocomposites, three different sized graphene oxide sheets, namely G1, G2 and G3 were used to fabricate a series of NR/GO nanocomposites by latex mixing. The results indicate that adding GO can remarkably increase the modulus of NR. The enhancement of modulus is strongly dependent on the size of GO sheets incorporated. G1 with smallest sheet size gives the maximum reinforcement effect compared with G2 and G3. Dynamic mechanical measurement and swelling ratios (Qf/Qg) indicate that G1 has stronger interfacial interaction with NR. XRD shows G1 is more effective in accelerating the strain-induced crystallization (SIC) of NR. The strong interfacial interaction facilitates the stress transfer and strain-induced crystallization, both of which lead to the improved modulus.http://www.expresspolymlett.com/letolt.php?file=EPL-0005915&mi=cdNanocompositesSize effectnatural rubberSICgraphene oxide
spellingShingle X. Wu
T. F. Lin
Z. H. Tang
B. C. Guo
G. S. Huang
Natural rubber/graphene oxide composites: Effect of sheet size on mechanical properties and strain-induced crystallization behavior
eXPRESS Polymer Letters
Nanocomposites
Size effect
natural rubber
SIC
graphene oxide
title Natural rubber/graphene oxide composites: Effect of sheet size on mechanical properties and strain-induced crystallization behavior
title_full Natural rubber/graphene oxide composites: Effect of sheet size on mechanical properties and strain-induced crystallization behavior
title_fullStr Natural rubber/graphene oxide composites: Effect of sheet size on mechanical properties and strain-induced crystallization behavior
title_full_unstemmed Natural rubber/graphene oxide composites: Effect of sheet size on mechanical properties and strain-induced crystallization behavior
title_short Natural rubber/graphene oxide composites: Effect of sheet size on mechanical properties and strain-induced crystallization behavior
title_sort natural rubber graphene oxide composites effect of sheet size on mechanical properties and strain induced crystallization behavior
topic Nanocomposites
Size effect
natural rubber
SIC
graphene oxide
url http://www.expresspolymlett.com/letolt.php?file=EPL-0005915&mi=cd
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AT tflin naturalrubbergrapheneoxidecompositeseffectofsheetsizeonmechanicalpropertiesandstraininducedcrystallizationbehavior
AT zhtang naturalrubbergrapheneoxidecompositeseffectofsheetsizeonmechanicalpropertiesandstraininducedcrystallizationbehavior
AT bcguo naturalrubbergrapheneoxidecompositeseffectofsheetsizeonmechanicalpropertiesandstraininducedcrystallizationbehavior
AT gshuang naturalrubbergrapheneoxidecompositeseffectofsheetsizeonmechanicalpropertiesandstraininducedcrystallizationbehavior