Fabrication and Analysis of Ion-Engineered ZnO Device Structures for Optoelectronic Applications

ZnO-based devices are highly promising for applications involving light-matter interaction. This work explores the impact of light-matter interaction on ion-induced ZnO structures and their respective energy band profiles. Incorporation of various ions, (Au<sup>&#x002B;</sup>, B<s...

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Bibliographic Details
Main Authors: Fareeha Younus, Ahmed Shuja, Muhammad Ali
Format: Article
Language:English
Published: IEEE 2023-01-01
Series:IEEE Photonics Journal
Subjects:
Online Access:https://ieeexplore.ieee.org/document/10229496/
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Summary:ZnO-based devices are highly promising for applications involving light-matter interaction. This work explores the impact of light-matter interaction on ion-induced ZnO structures and their respective energy band profiles. Incorporation of various ions, (Au<sup>&#x002B;</sup>, B<sup>&#x002B;</sup>, Cu<sup>&#x002B;</sup>, P<sup>&#x002B;</sup>) into the ZnO lattice, deposited via magnetron sputtering on an n-type Si substrate was investigated in detail. To assess the impact of these ions on the ZnO surface, monte-carlo simulations at low energies were performed and optimal ion dose and energy conditions were determined. The resulting post-fabrication devices underwent comprehensive structural, morphological, optical, and electrical diagnostics. X-ray diffraction (XRD) analysis confirmed the well-maintained crystal structure of the ZnO lattice along the &lt;100&gt; direction for all implant sequences. Notably, the gold (Au<sup>&#x002B;</sup>) implant exhibited the highest light extinction into the ZnO matrix, as indicated by the extinction coefficient and refractive index data. This observation suggested that Au<sup>&#x002B;</sup> implantation could effectively generate electron-hole pairs. The photovoltage and dark&#x002F;light current measurements provided further evidence of enhanced light-matter interactions and responsivity in the Au<sup>&#x002B;</sup>-implanted devices owing to light-induced currents. Furthermore, the energy bands of all implant cases were profiled by Charge Deep Level Transient Spectroscopy (Q-DLTS) measurements by evaluating discrete energy states within the ZnO lattice.
ISSN:1943-0655