Towards sustainable wastewater treatment: Cost and efficiency trade-offs in the photo-fenton process
This study examines the efficiency of COD removal in the photo-Fenton process, considering UVA irradiation, Fe2+ concentration, and H2O2 dosage as key operating variables. The primary objective is to simultaneously maximize COD removal and minimize operating costs using fuzzy optimization within a m...
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Elsevier
2025-09-01
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Online Access: | http://www.sciencedirect.com/science/article/pii/S2590123025022145 |
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author | Alec Nowell A. Ranara Redeil N. Arreza Trisha Kerstin C. Tan Kathleen B. Aviso Angelo Earvin Sy Choi |
author_facet | Alec Nowell A. Ranara Redeil N. Arreza Trisha Kerstin C. Tan Kathleen B. Aviso Angelo Earvin Sy Choi |
author_sort | Alec Nowell A. Ranara |
collection | DOAJ |
description | This study examines the efficiency of COD removal in the photo-Fenton process, considering UVA irradiation, Fe2+ concentration, and H2O2 dosage as key operating variables. The primary objective is to simultaneously maximize COD removal and minimize operating costs using fuzzy optimization within a multi-objective framework. Pareto-optimal solutions established COD removal efficiencies ranging from 10.54±1.81 % to 76.58±0.14 %, corresponding to costs of 147.02 to 2087.66 USD·m−3. Fuzzy optimization achieved a 71.12 % overall satisfaction level, balancing trade-offs between performance and cost. Optimal conditions were determined as 83.68 W·m−3 UVA irradiation, 0.4730 mM Fe2+, and 9.00 mM H2O2, yielding a 57.22±0.91 % COD removal at a total cost of 707.40 USD·m−3. This demonstrates a 2.48 times greater cost-efficiency than conventional methods, despite an 18.58 % lower removal efficiency. To improve the photo-Fenton process for industrial applications, future work can consider dynamic optimization for variable wastewater compositions, low-cost catalysts to reduce reagent expenses, hybrid systems to enhance scalability, and real-time monitoring to automate adjustments in irradiation and dosing. |
format | Article |
id | doaj-art-dcc1e931b6df419b920d29e7a8c0fbd4 |
institution | Matheson Library |
issn | 2590-1230 |
language | English |
publishDate | 2025-09-01 |
publisher | Elsevier |
record_format | Article |
series | Results in Engineering |
spelling | doaj-art-dcc1e931b6df419b920d29e7a8c0fbd42025-07-10T04:35:03ZengElsevierResults in Engineering2590-12302025-09-0127106142Towards sustainable wastewater treatment: Cost and efficiency trade-offs in the photo-fenton processAlec Nowell A. Ranara0Redeil N. Arreza1Trisha Kerstin C. Tan2Kathleen B. Aviso3Angelo Earvin Sy Choi4Department of Chemical Engineering, De La Salle University, 2401 Taft Avenue, Malate, Manila 0922, PhilippinesDepartment of Chemical Engineering, De La Salle University, 2401 Taft Avenue, Malate, Manila 0922, PhilippinesDepartment of Chemical Engineering, De La Salle University, 2401 Taft Avenue, Malate, Manila 0922, PhilippinesDepartment of Chemical Engineering, De La Salle University, 2401 Taft Avenue, Malate, Manila 0922, PhilippinesCorresponding author.; Department of Chemical Engineering, De La Salle University, 2401 Taft Avenue, Malate, Manila 0922, PhilippinesThis study examines the efficiency of COD removal in the photo-Fenton process, considering UVA irradiation, Fe2+ concentration, and H2O2 dosage as key operating variables. The primary objective is to simultaneously maximize COD removal and minimize operating costs using fuzzy optimization within a multi-objective framework. Pareto-optimal solutions established COD removal efficiencies ranging from 10.54±1.81 % to 76.58±0.14 %, corresponding to costs of 147.02 to 2087.66 USD·m−3. Fuzzy optimization achieved a 71.12 % overall satisfaction level, balancing trade-offs between performance and cost. Optimal conditions were determined as 83.68 W·m−3 UVA irradiation, 0.4730 mM Fe2+, and 9.00 mM H2O2, yielding a 57.22±0.91 % COD removal at a total cost of 707.40 USD·m−3. This demonstrates a 2.48 times greater cost-efficiency than conventional methods, despite an 18.58 % lower removal efficiency. To improve the photo-Fenton process for industrial applications, future work can consider dynamic optimization for variable wastewater compositions, low-cost catalysts to reduce reagent expenses, hybrid systems to enhance scalability, and real-time monitoring to automate adjustments in irradiation and dosing.http://www.sciencedirect.com/science/article/pii/S2590123025022145Chemical oxygen demandCost-effectivenessFuzzy optimizationPhoto-FentonTextile wastewater |
spellingShingle | Alec Nowell A. Ranara Redeil N. Arreza Trisha Kerstin C. Tan Kathleen B. Aviso Angelo Earvin Sy Choi Towards sustainable wastewater treatment: Cost and efficiency trade-offs in the photo-fenton process Results in Engineering Chemical oxygen demand Cost-effectiveness Fuzzy optimization Photo-Fenton Textile wastewater |
title | Towards sustainable wastewater treatment: Cost and efficiency trade-offs in the photo-fenton process |
title_full | Towards sustainable wastewater treatment: Cost and efficiency trade-offs in the photo-fenton process |
title_fullStr | Towards sustainable wastewater treatment: Cost and efficiency trade-offs in the photo-fenton process |
title_full_unstemmed | Towards sustainable wastewater treatment: Cost and efficiency trade-offs in the photo-fenton process |
title_short | Towards sustainable wastewater treatment: Cost and efficiency trade-offs in the photo-fenton process |
title_sort | towards sustainable wastewater treatment cost and efficiency trade offs in the photo fenton process |
topic | Chemical oxygen demand Cost-effectiveness Fuzzy optimization Photo-Fenton Textile wastewater |
url | http://www.sciencedirect.com/science/article/pii/S2590123025022145 |
work_keys_str_mv | AT alecnowellaranara towardssustainablewastewatertreatmentcostandefficiencytradeoffsinthephotofentonprocess AT redeilnarreza towardssustainablewastewatertreatmentcostandefficiencytradeoffsinthephotofentonprocess AT trishakerstinctan towardssustainablewastewatertreatmentcostandefficiencytradeoffsinthephotofentonprocess AT kathleenbaviso towardssustainablewastewatertreatmentcostandefficiencytradeoffsinthephotofentonprocess AT angeloearvinsychoi towardssustainablewastewatertreatmentcostandefficiencytradeoffsinthephotofentonprocess |