Effects of composition ratio of TiCu precursor on dealloying behavior in molten Mg and microstructural characteristics of Mg-Ti composites

Metal composites produced through the liquid metal dealloying (LMD) process feature an advanced matrix-matrix composite structure, where two metallic materials form a continuous, three-dimensional interconnected network. This study investigates the effects of TiCu precursor compositions on dealloyin...

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Hauptverfasser: Jee Eun Jang, Bo Hyun Park, Soo-Hyun Joo, Sung Hyuk Park
Format: Artikel
Sprache:Englisch
Veröffentlicht: KeAi Communications Co., Ltd. 2025-06-01
Schriftenreihe:Journal of Magnesium and Alloys
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Online-Zugang:http://www.sciencedirect.com/science/article/pii/S2213956725001215
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author Jee Eun Jang
Bo Hyun Park
Soo-Hyun Joo
Sung Hyuk Park
author_facet Jee Eun Jang
Bo Hyun Park
Soo-Hyun Joo
Sung Hyuk Park
author_sort Jee Eun Jang
collection DOAJ
description Metal composites produced through the liquid metal dealloying (LMD) process feature an advanced matrix-matrix composite structure, where two metallic materials form a continuous, three-dimensional interconnected network. This study investigates the effects of TiCu precursor compositions on dealloying behavior and microstructural evolution in liquid Mg, using Ti50Cu50 and Ti30Cu70 precursors. The initial microstructure of the precursor significantly influences dealloying kinetics and phase transitions. The single-phase Ti50Cu50 precursor exhibits a faster initial dealloying rate due to its homogeneous structure, yet complete dealloying requires 90 min. In contrast, the dual-phase Ti30Cu70 precursor achieves complete dealloying in 30 min, demonstrating the impact of a higher Cu concentration on accelerating the process kinetics. Additionally, the study explores the coarsening behavior and hardness variations during the LMD process, along with the microstructural characteristics of Mg-Ti composites fabricated from these two precursors. The findings highlight the critical role of precursor composition in tailoring the microstructure and properties of Mg-Ti composites produced through the LMD process, demonstrating its potential for advanced composite material manufacturing.
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spelling doaj-art-dbd3be17c98048fbbe3ed2ba2e9bbc212025-07-15T04:16:09ZengKeAi Communications Co., Ltd.Journal of Magnesium and Alloys2213-95672025-06-0113627842799Effects of composition ratio of TiCu precursor on dealloying behavior in molten Mg and microstructural characteristics of Mg-Ti compositesJee Eun Jang0Bo Hyun Park1Soo-Hyun Joo2Sung Hyuk Park3Department of Materials Science and Metallurgical Engineering, Kyungpook National University, Daegu 41566, Republic of Korea; Graduate School of Materials Science and Engineering, Kyungpook National University, Daegu 41566, Republic of KoreaDepartment of Materials Science and Metallurgical Engineering, Kyungpook National University, Daegu 41566, Republic of Korea; Graduate School of Materials Science and Engineering, Kyungpook National University, Daegu 41566, Republic of KoreaDepartment of Materials Science and Engineering, Dankook University, Cheonan 31116, Republic of Korea; Corresponding authors.Department of Materials Science and Metallurgical Engineering, Kyungpook National University, Daegu 41566, Republic of Korea; Graduate School of Materials Science and Engineering, Kyungpook National University, Daegu 41566, Republic of Korea; Corresponding authors.Metal composites produced through the liquid metal dealloying (LMD) process feature an advanced matrix-matrix composite structure, where two metallic materials form a continuous, three-dimensional interconnected network. This study investigates the effects of TiCu precursor compositions on dealloying behavior and microstructural evolution in liquid Mg, using Ti50Cu50 and Ti30Cu70 precursors. The initial microstructure of the precursor significantly influences dealloying kinetics and phase transitions. The single-phase Ti50Cu50 precursor exhibits a faster initial dealloying rate due to its homogeneous structure, yet complete dealloying requires 90 min. In contrast, the dual-phase Ti30Cu70 precursor achieves complete dealloying in 30 min, demonstrating the impact of a higher Cu concentration on accelerating the process kinetics. Additionally, the study explores the coarsening behavior and hardness variations during the LMD process, along with the microstructural characteristics of Mg-Ti composites fabricated from these two precursors. The findings highlight the critical role of precursor composition in tailoring the microstructure and properties of Mg-Ti composites produced through the LMD process, demonstrating its potential for advanced composite material manufacturing.http://www.sciencedirect.com/science/article/pii/S2213956725001215Liquid metal dealloyingPrecursor compositionMg-Ti composite3D interconnected structureHardness
spellingShingle Jee Eun Jang
Bo Hyun Park
Soo-Hyun Joo
Sung Hyuk Park
Effects of composition ratio of TiCu precursor on dealloying behavior in molten Mg and microstructural characteristics of Mg-Ti composites
Journal of Magnesium and Alloys
Liquid metal dealloying
Precursor composition
Mg-Ti composite
3D interconnected structure
Hardness
title Effects of composition ratio of TiCu precursor on dealloying behavior in molten Mg and microstructural characteristics of Mg-Ti composites
title_full Effects of composition ratio of TiCu precursor on dealloying behavior in molten Mg and microstructural characteristics of Mg-Ti composites
title_fullStr Effects of composition ratio of TiCu precursor on dealloying behavior in molten Mg and microstructural characteristics of Mg-Ti composites
title_full_unstemmed Effects of composition ratio of TiCu precursor on dealloying behavior in molten Mg and microstructural characteristics of Mg-Ti composites
title_short Effects of composition ratio of TiCu precursor on dealloying behavior in molten Mg and microstructural characteristics of Mg-Ti composites
title_sort effects of composition ratio of ticu precursor on dealloying behavior in molten mg and microstructural characteristics of mg ti composites
topic Liquid metal dealloying
Precursor composition
Mg-Ti composite
3D interconnected structure
Hardness
url http://www.sciencedirect.com/science/article/pii/S2213956725001215
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