Theoretical research of selective splitting of closo-dicarba-dodecaboranes(12) under action of ammonia
Reaction of splitting of carboranes (12) under action of ammonia were investigated by the B3PW91/6-31G(d,p) method. Separate stages of process are found and quantitatively characterized. Thermodynamic and kinetic parameters of reactions were calculated
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| Format: | Article |
| Language: | Russian |
| Published: |
MIREA - Russian Technological University
2007-08-01
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| Series: | Тонкие химические технологии |
| Online Access: | https://www.finechem-mirea.ru/jour/article/view/1331 |
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| _version_ | 1839581489314922496 |
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| author | S. P. Knyazev E. G. Gordeyev E. A. Chernyshev |
| author_facet | S. P. Knyazev E. G. Gordeyev E. A. Chernyshev |
| author_sort | S. P. Knyazev |
| collection | DOAJ |
| description | Reaction of splitting of carboranes (12) under action of ammonia were investigated by the B3PW91/6-31G(d,p) method. Separate stages of process are found and quantitatively characterized. Thermodynamic and kinetic parameters of reactions were calculated |
| format | Article |
| id | doaj-art-d6111c840b584789a7adf12f0eceb40a |
| institution | Matheson Library |
| issn | 2410-6593 2686-7575 |
| language | Russian |
| publishDate | 2007-08-01 |
| publisher | MIREA - Russian Technological University |
| record_format | Article |
| series | Тонкие химические технологии |
| spelling | doaj-art-d6111c840b584789a7adf12f0eceb40a2025-08-04T10:19:30ZrusMIREA - Russian Technological UniversityТонкие химические технологии2410-65932686-75752007-08-012466711326Theoretical research of selective splitting of closo-dicarba-dodecaboranes(12) under action of ammoniaS. P. Knyazev0E. G. Gordeyev1E. A. Chernyshev2M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571Reaction of splitting of carboranes (12) under action of ammonia were investigated by the B3PW91/6-31G(d,p) method. Separate stages of process are found and quantitatively characterized. Thermodynamic and kinetic parameters of reactions were calculatedhttps://www.finechem-mirea.ru/jour/article/view/1331 |
| spellingShingle | S. P. Knyazev E. G. Gordeyev E. A. Chernyshev Theoretical research of selective splitting of closo-dicarba-dodecaboranes(12) under action of ammonia Тонкие химические технологии |
| title | Theoretical research of selective splitting of closo-dicarba-dodecaboranes(12) under action of ammonia |
| title_full | Theoretical research of selective splitting of closo-dicarba-dodecaboranes(12) under action of ammonia |
| title_fullStr | Theoretical research of selective splitting of closo-dicarba-dodecaboranes(12) under action of ammonia |
| title_full_unstemmed | Theoretical research of selective splitting of closo-dicarba-dodecaboranes(12) under action of ammonia |
| title_short | Theoretical research of selective splitting of closo-dicarba-dodecaboranes(12) under action of ammonia |
| title_sort | theoretical research of selective splitting of closo dicarba dodecaboranes 12 under action of ammonia |
| url | https://www.finechem-mirea.ru/jour/article/view/1331 |
| work_keys_str_mv | AT spknyazev theoreticalresearchofselectivesplittingofclosodicarbadodecaboranes12underactionofammonia AT eggordeyev theoreticalresearchofselectivesplittingofclosodicarbadodecaboranes12underactionofammonia AT eachernyshev theoreticalresearchofselectivesplittingofclosodicarbadodecaboranes12underactionofammonia |