Velocity dispersion and attenuation of acoustic waves in critical mixtures
Theoretical considerations on critical ultrasonic dispersion and attenuation in binary liquid mixtures based on the mode-coupling approach and frequency-dependent heat capacity are presented. A general expression for the critical amplitude A (T) in terms of the parameter d = (ρc^0_v,x/Tα_p) x (dT_c/...
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Main Authors: | , |
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Format: | Article |
Language: | English |
Published: |
Institute of Fundamental Technological Research Polish Academy of Sciences
2014-05-01
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Series: | Archives of Acoustics |
Online Access: | https://acoustics.ippt.pan.pl/index.php/aa/article/view/1290 |
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Summary: | Theoretical considerations on critical ultrasonic dispersion and attenuation in binary liquid mixtures based on the mode-coupling approach and frequency-dependent heat capacity are presented. A general expression for the critical amplitude A (T) in terms of the parameter d = (ρc^0_v,x/Tα_p) x (dT_c/dP) is derived. It is shown that for specific values of d one obtains expressions for A (T) equivalent to those of Fixman, Kawasaki, Mistura and Chaban. Moreover, an experimental test has been carried out on the system methanol-n-hexane showing good agreement between our general expression for A (T) and experimental data. |
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ISSN: | 0137-5075 2300-262X |