Activity‐Selectivity Trends in Electrochemical Urea Synthesis: Co‐Reduction of CO2 and Nitrates Over Single‐Site Catalysts

QR-Code

Activity‐Selectivity Trends in Electrochemical Urea Synthesis: Co‐Reduction of CO2 and Nitrates Over Single‐Site Catalysts

Abstract Electrochemical co‐reduction of carbon dioxide and nitrates (CO2NO3RR) holds promise for sustainable urea production. However, the sluggish kinetics of the sixteen‐electron transfer and unclear mechanistic understanding strongly impede its development. Here, combined experimental and comput...

Ausführliche Beschreibung

Gespeichert in:

Bibliographische Detailangaben
Hauptverfasser:	Qinglan Zhao, Yushen Liu, Yuan Zhang, Shangqian Zhu, Hongming Xu, Mohammad Farhadpour, Fei Xiao, Minghui Xing, Dapeng Cao, Xueping Qin, Tejs Vegge, Minhua Shao
Format:	Artikel
Sprache:	Englisch
Veröffentlicht:	Wiley 2025-07-01
Schriftenreihe:	Advanced Science
Schlagworte:	activity‐selectivity trend C‐N coupling co‐reduction reaction electrocatalysis single‐site catalyst
Online-Zugang:	https://doi.org/10.1002/advs.202501882
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!

Ähnliche Einträge

Electrocatalytic CO2 reduction to C2+ products by non-Cu-based electrocatalysts: challenges and perspectives
von: Yuhang Ye, et al.
Veröffentlicht: (2025-01-01)

Selective electrocatalytic nitrate reduction to dinitrogen: Mechanisms, catalysts, and challenges
von: Jiayu Chen, et al.
Veröffentlicht: (2025-08-01)

Tetraethylammonium Cation Activates Fe for Selective Electroreduction of CO2 to Oxalate
von: Rohan Sartape, et al.
Veröffentlicht: (2025-07-01)

Synthesis of Self⁃Supported Pt@Ni(OH)2 Catalysts and Their Electrocatalytic Hydrogen Evolution Performance for Water Splitting
von: Kangsheng HUANG, et al.
Veröffentlicht: (2025-06-01)

Unsupported and carbon-supported silver catalysts for oxygen reduction reaction in alkaline media
von: Jonas Mart Linge, et al.
Veröffentlicht: (2025-09-01)

Electrochemical dealloying in ChCl-Urea Deep eutectic solvent: A strategy to fabricate porous FeCoNiAlMo high-entropy alloy with enhanced oxygen evolution reaction activity
von: Jiangfei Wang, et al.
Veröffentlicht: (2025-12-01)

Effect of calcination temperature on the performance of K-Co/Al2O3 catalyst for oxidative coupling of methane
von: Sarannuch Sringam, et al.
Veröffentlicht: (2025-06-01)

A Reexamination of CO2 Reduction with Fe2S2 Hydrogenase Mimics: Lessons in Using a Hydrogen Evolution Reaction Catalyst for CO2 to Formate Catalysis
von: Christopher J. Miller, et al.
Veröffentlicht: (2025-07-01)

Structure-property relations of heterophasic ethylene-propylene copolymers based on a single-site catalyst
von: M. Aarnio-Winterhof, et al.
Veröffentlicht: (2017-02-01)

Effect of adsorption-catalytic deformation and partial deactivation on the determination of the absolute activity of a liquid phase hydrogenation catalyst
von: A. V. Afineevskii, et al.
Veröffentlicht: (2023-10-01)

Cu-doped CeMnO2-supported Pt catalysts with high activity at industrial operating conditions for preferential CO oxidation in H2
von: Jianlin Cao, et al.
Veröffentlicht: (2025-06-01)

Cu@Pt Core–Shell Nanostructures for Ammonia Oxidation: Bridging Electrocatalysis and Electrochemical Sensing
von: Bommireddy Naveen, et al.
Veröffentlicht: (2025-07-01)

Catalyst handbook /
Veröffentlicht: (1989)

Catalyst Lifetime Analysis for High-Temperature Shift Converter (104-D1) at Urea Factory
von: Rahmatullah Rahmatullah, et al.
Veröffentlicht: (2023-11-01)

Structure of metallic catalysts /
von: Anderson, J. R. (John Russell), 1918 Oct. 23-
Veröffentlicht: (1975)

Nickel-Driven Electrochemical Upgrading of Kraft Lignin to Value-Added Aliphatic and Phenolic Products
von: Yanbing Liu, et al.
Veröffentlicht: (2025-06-01)

Mesoporous Co@MCM-41 catalyst for stable ethane dehydrogenation
von: Xiufang Wang, et al.
Veröffentlicht: (2025-06-01)

Biomass-Derived Catalysts with Dual Functions for Electrochemical Water Splitting
von: Wangchuang Zhu, et al.
Veröffentlicht: (2025-07-01)

Preparation and Characterization of Bimetallic Catalyst (NiO – CoO) for Desulfurization of Gas Oil
von: Baghdad Science Journal
Veröffentlicht: (2016-06-01)

Recent advancements in two-dimensional transition metal dichalcogenide materials towards hydrogen-evolution electrocatalysis
von: Jianmin Yu, et al.
Veröffentlicht: (2025-06-01)

Understanding catalyst deactivation in an industrial green hydrotreater and its correlation with catalyst composition
von: Elham Nejadmoghadam, et al.
Veröffentlicht: (2025-10-01)

Facile generation and regulation of oxygen vacancies in BiOCl catalysts for effectively photocatalytic degradation of Rhodamine B
von: Fei Pei, et al.
Veröffentlicht: (2025-07-01)

Preparing supported raney nickel catalysts by dip coating /
von: Oden, L. L.
Veröffentlicht: (1976)

Synergistic effects of promoters in Fe/YZrOx catalysts for CO2 hydrogenation to higher hydrocarbons
von: Laura Krausser, et al.
Veröffentlicht: (2025-06-01)

Electronic perturbation of Pd single-atom catalysts on graphdiyne derivatives toward effective electrocatalytic nitrate reduction
von: Cheng Wang, et al.
Veröffentlicht: (2025-08-01)

Trimerization of 1,2‐Diaminocyclohexane Catalyzed by a Metal–Organic Cage Tandem Catalyst with Dual Biomimetic Active Sites
von: Xiao‐Jun Chai, et al.
Veröffentlicht: (2025-07-01)

Ruthenium containing polyoxometalates: From synthesis, structures, properties to functional applications
von: Qingmiao Cai, et al.
Veröffentlicht: (2025-06-01)

First-Principle Investigation of Reaction Pathways for Nitrate Reduction on (101) Surface of Anatase TiO2
von: HE Xiyu, YANG Fan, ZHANG Junliang
Veröffentlicht: (2025-07-01)

Design of novel inverse ZrO2/Ni catalysts for CO2 utilization: From CO2 to syn-methane
von: Li Li, et al.
Veröffentlicht: (2025-09-01)

Heterogeneous alkaline calcium oxide nano-catalyst supported on porous materials for the transesterification reaction: A review
von: Asfaw Adeko Tigro, et al.
Veröffentlicht: (2025-09-01)

The study of phase composition of Cu-containing catalyst in the processes of purification of the water-methanol fraction and the conversion of CO
von: V. G. Shсhankina, et al.
Veröffentlicht: (2013-04-01)

Eggshell Waste Valorization into CaO/CaCO<sub>3</sub> Solid Base Catalysts
von: Matías G. Rinaudo, et al.
Veröffentlicht: (2024-09-01)

Recent Advances in Multi-Atom Catalysts for Sustainable Energy Applications
von: Qing Wang, et al.
Veröffentlicht: (2025-06-01)

NiCo(OH)<sub>2</sub>/NiCo<sub>2</sub>O<sub>4</sub> as a Heterogeneous Catalyst for the Electrooxidation of 5-Hydroxymethylfurfural
von: Wen Li, et al.
Veröffentlicht: (2025-06-01)

C–N coupling for 1,3,4-oxadiazole derivatives using RuPhos PdG4 catalyst: A Novel approach to efficient synthesis
von: Deepak Kumar, et al.
Veröffentlicht: (2025-07-01)

CO2 hydrogenation to value-added chemicals over mesoporous carbon-supported Trimetallic NiGaAg catalysts
von: Iman Abdullah, et al.
Veröffentlicht: (2025-12-01)

Heterogeneous Electrocatalytic CO2 Reduction by Supported Molecular Catalysts Well Dispersed on Electrode Surface
von: Ke Ma, et al.
Veröffentlicht: (2025-07-01)

Ligand Engineering of Co‐N4 Single‐Atom Catalysts for Highly‐Active and Stable Acidic Oxygen Evolution
von: Taeyoung Jeong, et al.
Veröffentlicht: (2025-07-01)

Non-Carbon-Supported, Pt-Based Catalysts with Applications in the Electrochemical Hydrogen Pump/Compressor (EHP/C)
von: Galin Rusev Borisov, et al.
Veröffentlicht: (2025-06-01)

Effect of Vulcanization Temperature on the Activity of NiW/Al2O3 Catalyst
von: Shasha GUO, et al.
Veröffentlicht: (2025-04-01)