Nuclear Magnetic Resonance in Tire Waste Mortars

This study aims to investigate the application of nuclear magnetic resonance (NMR) to characterize mortars containing recycled rubber waste as an eco-innovative material for sustainable construction. The primary objective was to analyze the way rubber granules influence hydration kinetics, microstru...

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Main Authors: Marta Ioana Moldoveanu, Daniela Lucia Manea, Elena Jumate, Raluca Iștoan, Radu Fechete, Tudor Panfil Toader
Format: Article
Language:English
Published: MDPI AG 2025-06-01
Series:Applied Sciences
Subjects:
Online Access:https://www.mdpi.com/2076-3417/15/12/6895
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author Marta Ioana Moldoveanu
Daniela Lucia Manea
Elena Jumate
Raluca Iștoan
Radu Fechete
Tudor Panfil Toader
author_facet Marta Ioana Moldoveanu
Daniela Lucia Manea
Elena Jumate
Raluca Iștoan
Radu Fechete
Tudor Panfil Toader
author_sort Marta Ioana Moldoveanu
collection DOAJ
description This study aims to investigate the application of nuclear magnetic resonance (NMR) to characterize mortars containing recycled rubber waste as an eco-innovative material for sustainable construction. The primary objective was to analyze the way rubber granules influence hydration kinetics, microstructural development and pore structure. The innovative mortar formulations incorporated rubber granules, casein, natural hydraulic lime (NHL), and latex. NMR analysis revealed distinct T<sub>2</sub> relaxation time distributions correlated with different pore sizes and water states: shorter T<sub>2</sub> values demonstrate strongly bound water in small pores, while longer T<sub>2</sub> values are associated with loosely bound or free water in larger pores. The formulation with 3.5% NHL and 5% rubber granules exhibited optimal microstructural characteristics. These results reveal that NMR is a valuable, non-destructive tool for monitoring cementitious material evolution and supporting the use of tire-derived waste in eco-innovative mortar designs.
format Article
id doaj-art-abb1c6ec08b84e708c3bb7fe8996f1a2
institution Matheson Library
issn 2076-3417
language English
publishDate 2025-06-01
publisher MDPI AG
record_format Article
series Applied Sciences
spelling doaj-art-abb1c6ec08b84e708c3bb7fe8996f1a22025-06-25T13:26:48ZengMDPI AGApplied Sciences2076-34172025-06-011512689510.3390/app15126895Nuclear Magnetic Resonance in Tire Waste MortarsMarta Ioana Moldoveanu0Daniela Lucia Manea1Elena Jumate2Raluca Iștoan3Radu Fechete4Tudor Panfil Toader5Faculty of Civil Engineering, Technical University of Cluj-Napoca, 28 Memorandumului Street, 400114 Cluj-Napoca, RomaniaFaculty of Civil Engineering, Technical University of Cluj-Napoca, 28 Memorandumului Street, 400114 Cluj-Napoca, RomaniaFaculty of Civil Engineering, Technical University of Cluj-Napoca, 28 Memorandumului Street, 400114 Cluj-Napoca, RomaniaFaculty of Civil Engineering, Technical University of Cluj-Napoca, 28 Memorandumului Street, 400114 Cluj-Napoca, RomaniaFaculty of Materials and Environmental Engineering, Technical University of Cluj-Napoca, 25 George Barițiu Street, 400027 Cluj-Napoca, RomaniaNational Institute for Research and Development in Construction, Urban Planning and Sustainable Spatial Development (URBAN-INCERC), Cluj-Napoca Branch, 117 Calea Floresti, 400524 Cluj-Napoca, RomaniaThis study aims to investigate the application of nuclear magnetic resonance (NMR) to characterize mortars containing recycled rubber waste as an eco-innovative material for sustainable construction. The primary objective was to analyze the way rubber granules influence hydration kinetics, microstructural development and pore structure. The innovative mortar formulations incorporated rubber granules, casein, natural hydraulic lime (NHL), and latex. NMR analysis revealed distinct T<sub>2</sub> relaxation time distributions correlated with different pore sizes and water states: shorter T<sub>2</sub> values demonstrate strongly bound water in small pores, while longer T<sub>2</sub> values are associated with loosely bound or free water in larger pores. The formulation with 3.5% NHL and 5% rubber granules exhibited optimal microstructural characteristics. These results reveal that NMR is a valuable, non-destructive tool for monitoring cementitious material evolution and supporting the use of tire-derived waste in eco-innovative mortar designs.https://www.mdpi.com/2076-3417/15/12/6895nuclear magnetic resonancetire wastehydrationrubber granulesfree watermortar structure
spellingShingle Marta Ioana Moldoveanu
Daniela Lucia Manea
Elena Jumate
Raluca Iștoan
Radu Fechete
Tudor Panfil Toader
Nuclear Magnetic Resonance in Tire Waste Mortars
Applied Sciences
nuclear magnetic resonance
tire waste
hydration
rubber granules
free water
mortar structure
title Nuclear Magnetic Resonance in Tire Waste Mortars
title_full Nuclear Magnetic Resonance in Tire Waste Mortars
title_fullStr Nuclear Magnetic Resonance in Tire Waste Mortars
title_full_unstemmed Nuclear Magnetic Resonance in Tire Waste Mortars
title_short Nuclear Magnetic Resonance in Tire Waste Mortars
title_sort nuclear magnetic resonance in tire waste mortars
topic nuclear magnetic resonance
tire waste
hydration
rubber granules
free water
mortar structure
url https://www.mdpi.com/2076-3417/15/12/6895
work_keys_str_mv AT martaioanamoldoveanu nuclearmagneticresonanceintirewastemortars
AT danielaluciamanea nuclearmagneticresonanceintirewastemortars
AT elenajumate nuclearmagneticresonanceintirewastemortars
AT ralucaistoan nuclearmagneticresonanceintirewastemortars
AT radufechete nuclearmagneticresonanceintirewastemortars
AT tudorpanfiltoader nuclearmagneticresonanceintirewastemortars