Femtosecond laser photochemical reduction of silver ion solution for micro-welding of transparent and hard materials for solar cell packaging

Transparent and hard materials are extensively employed in the fabrication of integrated devices. Ultrafast laser micro-welding technology serves as an efficient method for joining such materials. However, initiating multiphoton absorption in transparent materials necessitates high pulse energy, and...

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Bibliographic Details
Main Authors: Hao Chen, Zhaoxu Li, Mingyang Han, Xiao Yang, Zhimin Liang, Shi Bai
Format: Article
Language:English
Published: Elsevier 2025-08-01
Series:Materials & Design
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Online Access:http://www.sciencedirect.com/science/article/pii/S0264127525007762
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Summary:Transparent and hard materials are extensively employed in the fabrication of integrated devices. Ultrafast laser micro-welding technology serves as an efficient method for joining such materials. However, initiating multiphoton absorption in transparent materials necessitates high pulse energy, and a polished surface forming optical contact is crucial for ensuring reliable laser welding. Consequently, achieving high-quality connections of transparent materials under non-optical contact conditions presents a challenge. In this study, a silver ion solution was utilized as an intermediate layer for femtosecond laser micro-welding of glass and heterogeneous materials. The findings demonstrated that photochemically reduced silver nanoclusters increased the shear strength of glass to 27.36 MPa at a low input energy density (2.4J/cm2). Furthermore, the quality of the connection and sealing reliability were assessed through thermal shock and waterproof evaluations. The results indicated that femtosecond laser welding assisted by a silver ion solution is an effective and energy-efficient technique for achieving high-quality connections of non-optically contacted transparent materials, offering a promising approach for applications such as solar cell packaging.
ISSN:0264-1275