Study of structure features and properties of thermodifusion heat resistant coatings on copper

The article presents data on the features of the structure and properties of heat-resistant layers obtained by thermal diffusion aluminization and siliconization of copper (grade M1) in powder saturating media. The phase composition of the diffusion layers has been investigated, in particular, it ha...

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Main Authors: V. M. Konstantinov, V. G. Dashkevich, I. V. Pletenev
Format: Article
Language:English
Published: Belarusian National Technical University 2021-03-01
Series:Литьë и металлургия
Subjects:
Online Access:https://lim.bntu.by/jour/article/view/3310
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author V. M. Konstantinov
V. G. Dashkevich
I. V. Pletenev
author_facet V. M. Konstantinov
V. G. Dashkevich
I. V. Pletenev
author_sort V. M. Konstantinov
collection DOAJ
description The article presents data on the features of the structure and properties of heat-resistant layers obtained by thermal diffusion aluminization and siliconization of copper (grade M1) in powder saturating media. The phase composition of the diffusion layers has been investigated, in particular, it has been established that, as a result of aluminization, a heterogeneous structure of the diffusion layer is formed with the participation of Cu3Al and Cu9Al4 aluminides. The data on heat resistance under test conditions with a total duration of 25 hours and a temperature of 800 °C are given. Tests have shown that the best protective properties are possessed by aluminized diffusion layers, which are characterized by a higher sink rate against high-temperature oxidation and cyclic heating conditions. According to the results of the analysis of the microstructures before and after oxidation, the features of the protective action and destruction of the aluminized and silicified diffusion layers were noted. On aluminized specimens, during heat resistance tests, the layer thickness grows deep into the specimen and the aluminum concentration gradually redistributes. For siliconized diffusion layers, a loss of continuity of the protective layer by peeling off sections (swelling) and the appearance of focal of layer corrosion with a test duration of more than 15 h were noted.
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issn 1683-6065
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language English
publishDate 2021-03-01
publisher Belarusian National Technical University
record_format Article
series Литьë и металлургия
spelling doaj-art-a0b547901a7e48e7a23efd929a083ba22025-08-04T16:50:35ZengBelarusian National Technical UniversityЛитьë и металлургия1683-60652414-04062021-03-010112412910.21122/1683-6065-2021-1-124-1293200Study of structure features and properties of thermodifusion heat resistant coatings on copperV. M. Konstantinov0V. G. Dashkevich1I. V. Pletenev2Belarusian National Technical UniversityBelarusian National Technical UniversityBelarusian National Technical UniversityThe article presents data on the features of the structure and properties of heat-resistant layers obtained by thermal diffusion aluminization and siliconization of copper (grade M1) in powder saturating media. The phase composition of the diffusion layers has been investigated, in particular, it has been established that, as a result of aluminization, a heterogeneous structure of the diffusion layer is formed with the participation of Cu3Al and Cu9Al4 aluminides. The data on heat resistance under test conditions with a total duration of 25 hours and a temperature of 800 °C are given. Tests have shown that the best protective properties are possessed by aluminized diffusion layers, which are characterized by a higher sink rate against high-temperature oxidation and cyclic heating conditions. According to the results of the analysis of the microstructures before and after oxidation, the features of the protective action and destruction of the aluminized and silicified diffusion layers were noted. On aluminized specimens, during heat resistance tests, the layer thickness grows deep into the specimen and the aluminum concentration gradually redistributes. For siliconized diffusion layers, a loss of continuity of the protective layer by peeling off sections (swelling) and the appearance of focal of layer corrosion with a test duration of more than 15 h were noted.https://lim.bntu.by/jour/article/view/3310аluminizingsiliconizingincreasing the heat resistance of coppercopper water-cooled refrigerators for glass production.
spellingShingle V. M. Konstantinov
V. G. Dashkevich
I. V. Pletenev
Study of structure features and properties of thermodifusion heat resistant coatings on copper
Литьë и металлургия
аluminizing
siliconizing
increasing the heat resistance of copper
copper water-cooled refrigerators for glass production.
title Study of structure features and properties of thermodifusion heat resistant coatings on copper
title_full Study of structure features and properties of thermodifusion heat resistant coatings on copper
title_fullStr Study of structure features and properties of thermodifusion heat resistant coatings on copper
title_full_unstemmed Study of structure features and properties of thermodifusion heat resistant coatings on copper
title_short Study of structure features and properties of thermodifusion heat resistant coatings on copper
title_sort study of structure features and properties of thermodifusion heat resistant coatings on copper
topic аluminizing
siliconizing
increasing the heat resistance of copper
copper water-cooled refrigerators for glass production.
url https://lim.bntu.by/jour/article/view/3310
work_keys_str_mv AT vmkonstantinov studyofstructurefeaturesandpropertiesofthermodifusionheatresistantcoatingsoncopper
AT vgdashkevich studyofstructurefeaturesandpropertiesofthermodifusionheatresistantcoatingsoncopper
AT ivpletenev studyofstructurefeaturesandpropertiesofthermodifusionheatresistantcoatingsoncopper