Synthesis and Characterization of Some New Benzodiazepinium Salt Derivatives under microwave Irradiation
An attempt to synthesize the benzoimidazol derivatives from the reaction of o-phenylenediamine and benzoic acid derivatives in the presence of ethanol and various ketones under microwave irradiation, 1 , 5 - benzodiazepinum salt derivatives were obtained instead of them. Unexpected...
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| Format: | Article |
| Language: | English |
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University of Baghdad, College of Science for Women
2015-12-01
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| Series: | مجلة بغداد للعلوم |
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| Online Access: | http://bsj.uobaghdad.edu.iq/index.php/BSJ/article/view/2123 |
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| author | Baghdad Science Journal |
| author_facet | Baghdad Science Journal |
| author_sort | Baghdad Science Journal |
| collection | DOAJ |
| description | An attempt to synthesize the benzoimidazol derivatives from the reaction of o-phenylenediamine and benzoic acid derivatives in the presence of ethanol and various ketones under microwave irradiation, 1 , 5 - benzodiazepinum salt derivatives were obtained instead of them. Unexpected reaction was happened for synthesis a new series of benzodiazepinium salt derivatives in a selective yield . The reaction mechanism was also discussed. The new compounds were purified and identified their structures were elucidated using various physical techniques like; FT- IR spectra, micro elemental analysis (C.H.N) and 1H NMR spectra. |
| format | Article |
| id | doaj-art-970a8cc68d564d858fb6dbfb8a2847f0 |
| institution | Matheson Library |
| issn | 2078-8665 2411-7986 |
| language | English |
| publishDate | 2015-12-01 |
| publisher | University of Baghdad, College of Science for Women |
| record_format | Article |
| series | مجلة بغداد للعلوم |
| spelling | doaj-art-970a8cc68d564d858fb6dbfb8a2847f02025-08-02T14:28:20ZengUniversity of Baghdad, College of Science for Womenمجلة بغداد للعلوم2078-86652411-79862015-12-0112410.21123/bsj.12.4.753-760Synthesis and Characterization of Some New Benzodiazepinium Salt Derivatives under microwave IrradiationBaghdad Science JournalAn attempt to synthesize the benzoimidazol derivatives from the reaction of o-phenylenediamine and benzoic acid derivatives in the presence of ethanol and various ketones under microwave irradiation, 1 , 5 - benzodiazepinum salt derivatives were obtained instead of them. Unexpected reaction was happened for synthesis a new series of benzodiazepinium salt derivatives in a selective yield . The reaction mechanism was also discussed. The new compounds were purified and identified their structures were elucidated using various physical techniques like; FT- IR spectra, micro elemental analysis (C.H.N) and 1H NMR spectra.http://bsj.uobaghdad.edu.iq/index.php/BSJ/article/view/2123Benzodiazepinium Salt, Microwave Irradiation, Characterization. |
| spellingShingle | Baghdad Science Journal Synthesis and Characterization of Some New Benzodiazepinium Salt Derivatives under microwave Irradiation مجلة بغداد للعلوم Benzodiazepinium Salt, Microwave Irradiation, Characterization. |
| title | Synthesis and Characterization of Some New Benzodiazepinium Salt Derivatives under microwave Irradiation |
| title_full | Synthesis and Characterization of Some New Benzodiazepinium Salt Derivatives under microwave Irradiation |
| title_fullStr | Synthesis and Characterization of Some New Benzodiazepinium Salt Derivatives under microwave Irradiation |
| title_full_unstemmed | Synthesis and Characterization of Some New Benzodiazepinium Salt Derivatives under microwave Irradiation |
| title_short | Synthesis and Characterization of Some New Benzodiazepinium Salt Derivatives under microwave Irradiation |
| title_sort | synthesis and characterization of some new benzodiazepinium salt derivatives under microwave irradiation |
| topic | Benzodiazepinium Salt, Microwave Irradiation, Characterization. |
| url | http://bsj.uobaghdad.edu.iq/index.php/BSJ/article/view/2123 |
| work_keys_str_mv | AT baghdadsciencejournal synthesisandcharacterizationofsomenewbenzodiazepiniumsaltderivativesundermicrowaveirradiation |