Hydrogen-air Combustion Limits at Low and Cryogenic Temperatures

The effective advancement and societal acceptance of new LH2 systems and technologies depend on a comprehensive understanding of their safety levels. Beyond the general safety principles associated with LH2 solutions, it is essential to have detailed knowledge of their safety attributes, including c...

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Main Authors: Igor A. Kirillov, Vadim Yu. Plaksin
Format: Article
Language:English
Published: AIDIC Servizi S.r.l. 2025-06-01
Series:Chemical Engineering Transactions
Online Access:https://www.cetjournal.it/index.php/cet/article/view/15235
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author Igor A. Kirillov
Vadim Yu. Plaksin
author_facet Igor A. Kirillov
Vadim Yu. Plaksin
author_sort Igor A. Kirillov
collection DOAJ
description The effective advancement and societal acceptance of new LH2 systems and technologies depend on a comprehensive understanding of their safety levels. Beyond the general safety principles associated with LH2 solutions, it is essential to have detailed knowledge of their safety attributes, including concentration, pressure, and temperature limits. While well-established data exists for hydrogen-air combustion concentration limits at standard and elevated temperatures, there is a notable lack of information regarding these limits at low and cryogenic temperatures. This report aims to provide an exhaustive review of two categories of hydrogen-air combustion limits: concentration and temperature. It first highlights the existing gaps and deficiencies in the available empirical concentration limits for temperatures ranging from 90 K to 850 K. Following this, it introduces fundamental limits for detonation flames, deflagration flames, and flame balls, which are consistent regardless of the testing facility, methodology, or measurement standards. These fundamental limits help clarify some previously recorded experimental findings and shed light on the relationship between empirical and theoretical concentration limits. Additionally, the report makes a qualitative prediction of a newly identified combustion phenomenon referred to by the authors as the "cryogenic temperature limit for hydrogen combustion." Lastly, it offers practical suggestions for conservatively estimating the concentration limits of flames that could trigger fast turbulent or detonating flames at low and cryogenic temperatures, presented through an analytical correlation.
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spelling doaj-art-8f2fdb24ab5b4b9fb7b9c55128b4aeb82025-06-30T06:36:30ZengAIDIC Servizi S.r.l.Chemical Engineering Transactions2283-92162025-06-01116Hydrogen-air Combustion Limits at Low and Cryogenic TemperaturesIgor A. KirillovVadim Yu. PlaksinThe effective advancement and societal acceptance of new LH2 systems and technologies depend on a comprehensive understanding of their safety levels. Beyond the general safety principles associated with LH2 solutions, it is essential to have detailed knowledge of their safety attributes, including concentration, pressure, and temperature limits. While well-established data exists for hydrogen-air combustion concentration limits at standard and elevated temperatures, there is a notable lack of information regarding these limits at low and cryogenic temperatures. This report aims to provide an exhaustive review of two categories of hydrogen-air combustion limits: concentration and temperature. It first highlights the existing gaps and deficiencies in the available empirical concentration limits for temperatures ranging from 90 K to 850 K. Following this, it introduces fundamental limits for detonation flames, deflagration flames, and flame balls, which are consistent regardless of the testing facility, methodology, or measurement standards. These fundamental limits help clarify some previously recorded experimental findings and shed light on the relationship between empirical and theoretical concentration limits. Additionally, the report makes a qualitative prediction of a newly identified combustion phenomenon referred to by the authors as the "cryogenic temperature limit for hydrogen combustion." Lastly, it offers practical suggestions for conservatively estimating the concentration limits of flames that could trigger fast turbulent or detonating flames at low and cryogenic temperatures, presented through an analytical correlation.https://www.cetjournal.it/index.php/cet/article/view/15235
spellingShingle Igor A. Kirillov
Vadim Yu. Plaksin
Hydrogen-air Combustion Limits at Low and Cryogenic Temperatures
Chemical Engineering Transactions
title Hydrogen-air Combustion Limits at Low and Cryogenic Temperatures
title_full Hydrogen-air Combustion Limits at Low and Cryogenic Temperatures
title_fullStr Hydrogen-air Combustion Limits at Low and Cryogenic Temperatures
title_full_unstemmed Hydrogen-air Combustion Limits at Low and Cryogenic Temperatures
title_short Hydrogen-air Combustion Limits at Low and Cryogenic Temperatures
title_sort hydrogen air combustion limits at low and cryogenic temperatures
url https://www.cetjournal.it/index.php/cet/article/view/15235
work_keys_str_mv AT igorakirillov hydrogenaircombustionlimitsatlowandcryogenictemperatures
AT vadimyuplaksin hydrogenaircombustionlimitsatlowandcryogenictemperatures