Experimental Attempts at and Theoretical Study of the Thermal Generation of <i>o</i>-Carborane-Supported N-Heterocyclic Carbenes

Experimental Attempts at and Theoretical Study of the Thermal Generation of <i>o</i>-Carborane-Supported N-Heterocyclic Carbenes

N-Heterocyclic carbenes (NHCs) have been widely utilized over the past three decades due to their broad applications, yet synthetic methods for their preparation remain limited. A promising approach for NHC generation involves the thermolysis of NHC adducts. Herein, we report the synthesis of NHC pe...

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Bibliographic Details
Main Authors: Mei-Juan Liang, Ke-Cheng Chen, Zhongzheng Cui, Yan-Chang Zhou, Yan Wang, Fan Qi, Xu-Qiong Xiao
Format: Article
Language:English
Published: MDPI AG 2025-05-01
Series:Inorganics
Subjects:
carborane
N-heterocyclic carbene
thermal generation
DFT calculation
Online Access:https://www.mdpi.com/2304-6740/13/6/179
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