Formylation of metallocomplexes of p- and m-tetraanizylporphyrins
The Vilsmeyer formylation reaction a of metallocomplexes of m- and p- methoxy-substituted tetraphenylporphyrins was investigated. Formyl derivatives of m-isomers were shown to form cyclization products not only in solutions but in solid state. Ability to such transformations decreases in a number Co...
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Format: | Article |
Language: | Russian |
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MIREA - Russian Technological University
2006-08-01
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Series: | Тонкие химические технологии |
Online Access: | https://www.finechem-mirea.ru/jour/article/view/1431 |
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author | S. V. Tsukanov V. D. Rumyantseva A. F. Mironov |
author_facet | S. V. Tsukanov V. D. Rumyantseva A. F. Mironov |
author_sort | S. V. Tsukanov |
collection | DOAJ |
description | The Vilsmeyer formylation reaction a of metallocomplexes of m- and p- methoxy-substituted tetraphenylporphyrins was investigated. Formyl derivatives of m-isomers were shown to form cyclization products not only in solutions but in solid state. Ability to such transformations decreases in a number Co>Cu>Ni>Pd>Pt. |
format | Article |
id | doaj-art-8c47f73f2fe34f8fb14ba38536a6c8e1 |
institution | Matheson Library |
issn | 2410-6593 2686-7575 |
language | Russian |
publishDate | 2006-08-01 |
publisher | MIREA - Russian Technological University |
record_format | Article |
series | Тонкие химические технологии |
spelling | doaj-art-8c47f73f2fe34f8fb14ba38536a6c8e12025-08-04T10:19:30ZrusMIREA - Russian Technological UniversityТонкие химические технологии2410-65932686-75752006-08-011471751426Formylation of metallocomplexes of p- and m-tetraanizylporphyrinsS. V. Tsukanov0V. D. Rumyantseva1A. F. Mironov2M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571The Vilsmeyer formylation reaction a of metallocomplexes of m- and p- methoxy-substituted tetraphenylporphyrins was investigated. Formyl derivatives of m-isomers were shown to form cyclization products not only in solutions but in solid state. Ability to such transformations decreases in a number Co>Cu>Ni>Pd>Pt.https://www.finechem-mirea.ru/jour/article/view/1431 |
spellingShingle | S. V. Tsukanov V. D. Rumyantseva A. F. Mironov Formylation of metallocomplexes of p- and m-tetraanizylporphyrins Тонкие химические технологии |
title | Formylation of metallocomplexes of p- and m-tetraanizylporphyrins |
title_full | Formylation of metallocomplexes of p- and m-tetraanizylporphyrins |
title_fullStr | Formylation of metallocomplexes of p- and m-tetraanizylporphyrins |
title_full_unstemmed | Formylation of metallocomplexes of p- and m-tetraanizylporphyrins |
title_short | Formylation of metallocomplexes of p- and m-tetraanizylporphyrins |
title_sort | formylation of metallocomplexes of p and m tetraanizylporphyrins |
url | https://www.finechem-mirea.ru/jour/article/view/1431 |
work_keys_str_mv | AT svtsukanov formylationofmetallocomplexesofpandmtetraanizylporphyrins AT vdrumyantseva formylationofmetallocomplexesofpandmtetraanizylporphyrins AT afmironov formylationofmetallocomplexesofpandmtetraanizylporphyrins |