(S,S)-Diiodido{3,3′-methylenebis[1-(1-hydroxy-4-methylpentan-2-yl)imidazol-2-ylene]}palladium(II) ethanol monosolvate
The structure of the title solvated bis-N-heterocyclic carbene palladium(II) complex, [PdI2(C19H32N4O2)2·C2H6O, exhibits a slightly distorted square-planar coordination at the palladium(II) atom, with the six-membered chelate ring adopting a boat conformation. One disordered ethanol solvent molecule...
Bewaard in:
| Hoofdauteurs: | , , , , |
|---|---|
| Formaat: | Artikel |
| Taal: | Engels |
| Gepubliceerd in: |
International Union of Crystallography
2025-06-01
|
| Reeks: | IUCrData |
| Onderwerpen: | |
| Online toegang: | https://journals.iucr.org/paper?S2414314625004237 |
| Tags: |
Voeg label toe
Geen labels, Wees de eerste die dit record labelt!
|
| Samenvatting: | The structure of the title solvated bis-N-heterocyclic carbene palladium(II) complex, [PdI2(C19H32N4O2)2·C2H6O, exhibits a slightly distorted square-planar coordination at the palladium(II) atom, with the six-membered chelate ring adopting a boat conformation. One disordered ethanol solvent molecule was co-crystallized. There are intermolecular O—H...O hydrogen bonds in the structure. The chiral centers of the precursor imidazolium salt was preserved during the metalation process. |
|---|---|
| ISSN: | 2414-3146 |