Asymmetric synthesis of allylic sulfonamides with axially and central chirality via palladium-catalyzed of atroposelective N-allylic alkylation

Asymmetric synthesis of allylic sulfonamides with axially and central chirality via palladium-catalyzed of atroposelective N-allylic alkylation

Axially chiral anilide compounds are an emerging but scarcely investigated class of stereogenic molecules with potential applications as chiral catalysts, biologically active scaffolds and functional materials. Compared to the C–C axially chiral molecules, the synthesis of axially chiral anilide com...

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Bibliographic Details
Main Authors: Dayuan Wang, Jiayi Zong, Bowen Wang, Longwu Sun, Xiao Xiao, Huri Piao, Miaolin Ke, Fener Chen
Format: Article
Language:English
Published: KeAi Communications Co. Ltd. 2025-05-01
Series:Green Synthesis and Catalysis
Subjects:
C-N axial chirality
Central chirality
Asymmetric catalysis
Sulfonamides
Allylic alkylation
Online Access:http://www.sciencedirect.com/science/article/pii/S2666554924000619
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