Synthesis, X-ray crystallography, spectroscopic characterizations, and density functional theory of the chloride-bound five-coordinate high-spin Iron(II) “Picket Fence” porphyrin complex

Synthesis, X-ray crystallography, spectroscopic characterizations, and density functional theory of the chloride-bound five-coordinate high-spin Iron(II) “Picket Fence” porphyrin complex

An Fe(II)-chlorido five-coordinate picket fence porphyrin complex with the formula [K (crypt-222)][FeII(TpivPP)Cl]·C6H5Cl (I) (where TpivPP is the picket fence porphyrin and crypt-222 is the cryptand-222) has been synthesized and characterized. Cryptand-222 was used to solubilize potassium chloride...

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Bibliographic Details
Main Authors: Feriel Salhi, Mondher Dhifet, Bouzid Gassoumi, Noureddine Issaoui, Habib Nasri
Format: Article
Language:English
Published: Frontiers Media S.A. 2025-07-01
Series:Frontiers in Chemistry
Subjects:
high-spin iron(II) porphyrin
X-ray molecular structure
UV–visible spectroscopy
IR spectroscopy
DFT calculation and MEP
NCI-RDG analyses
Online Access:https://www.frontiersin.org/articles/10.3389/fchem.2025.1607585/full
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