Catalytic cycloaddition of acrylates to norbornadiene. Kinetics and mechanism

Kinetics of [2+2+2]-cycloaddition of acrylates to norbornadiene in the presence of η3-bis(allyl) nickel was studied. The thermodynamic parameters were determined. Kinetics equations for all of the isomer reaction products were found. The data obtained agree with the formerly proposed mechanism.

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Bibliographic Details
Main Authors: I. E. Efros, O. A. Nikityuk, D. V. Dmitriev, V. R. Flid
Format: Article
Language:Russian
Published: MIREA - Russian Technological University 2010-10-01
Series:Тонкие химические технологии
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Online Access:https://www.finechem-mirea.ru/jour/article/view/932
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