Preparation of a bio-based epoxy with comparable properties to those of petroleum-based counterparts

In this paper a bio-based epoxy with outstanding thermal and mechanical properties was synthesized using a rosin-based epoxy monomer and a rosin-based curing agent. The chemical structures of rosin based epoxy monomer and curing agent were confirmed by Nuclear Magnetic Resonance (NMR) and Fourier Tr...

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Bibliographic Details
Main Authors: X. Q. Liu, W. Huang, Y. H. Jiang, J. Zhu, C. Z. Zhang
Format: Article
Language:English
Published: Budapest University of Technology and Economics 2012-04-01
Series:eXPRESS Polymer Letters
Subjects:
Online Access:http://www.expresspolymlett.com/letolt.php?file=EPL-0002948&mi=cd
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Summary:In this paper a bio-based epoxy with outstanding thermal and mechanical properties was synthesized using a rosin-based epoxy monomer and a rosin-based curing agent. The chemical structures of rosin based epoxy monomer and curing agent were confirmed by Nuclear Magnetic Resonance (NMR) and Fourier Transform Infrared (FT-IR) spectra. The flexural mechanical and dynamic mechanical properties as well as thermal stability of the cured epoxy were investigated. The results showed that the cured epoxy exhibited a glass transition temperature (Tg) of 164°C and its flexural strength and modulus were as high as 70 and 2200 MPa, respectively. This indicated that a wholly bio-based epoxy resin possessing high performance was successfully obtained.
ISSN:1788-618X