The thermolysis of ruthenium(II, III) ammine complexes in water solutions at the increased temperatures and the solid phase.
In this work reactions of the hexaammine ruthenium(II) - [Ru(NH3)6]Cl2 and “ruthenium red” -[Ru3O2(NH3)14]Cl6 • 4Н2О chlorides in the water alkaline solution at 190˚С (autoclave) and in the solid phase are investigated. The mechanism of restoration of the ruthenium ion by inside sphere ammonia up to...
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Main Authors: | E. V. Fesik, V. V. Grebnev, G. D. Malchikov |
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Format: | Article |
Language: | Russian |
Published: |
MIREA - Russian Technological University
2008-06-01
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Series: | Тонкие химические технологии |
Online Access: | https://www.finechem-mirea.ru/jour/article/view/1503 |
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