Characterization of Multi-Pass Enhanced Raman Spectroscopy for Gaseous Measurement
With the rise in global temperatures, it is of great significance to achieve rapid and accurate detection of greenhouse gases, such as carbon dioxide and methane. Raman spectroscopy not only overcomes the weakness of absorption spectroscopy in simultaneously measuring homonuclear diatomic molecules...
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2025-04-01
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| author | Miao Fan Huinan Yang Jun Chen |
| author_facet | Miao Fan Huinan Yang Jun Chen |
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| description | With the rise in global temperatures, it is of great significance to achieve rapid and accurate detection of greenhouse gases, such as carbon dioxide and methane. Raman spectroscopy not only overcomes the weakness of absorption spectroscopy in simultaneously measuring homonuclear diatomic molecules but also enables the simultaneous detection of multiple gases using a single-wavelength laser. However, due to the small Raman scattering cross-section and weak intensity of molecules, its application in gas detection is limited. To enhance the intensity of Raman scattering, this paper designs and constructs a multi-pass enhanced Raman spectroscopy setup. This study focuses on the effects of Raman scattering collection geometry, laser multi-pass patterns, and laser polarization relative to the Raman collection direction on signal intensity. Investigations into Raman scattering collection angles of 30°, 60°, and 90° reveal that the Raman scattering signal intensity increases as the collection angle decreases. Different laser multi-pass patterns also impact the signal, with the near-concentric linear multi-pass pattern found to collect more signals. To minimize the influence of excitation light on the signal, a side collection system is employed. Experiments show that the Raman scattering signal is stronger when the laser polarization is perpendicular to the collection direction. This study achieves overall system performance enhancement through coordinated optimization of multiple physical mechanisms, including Raman scattering collection geometry, laser multi-pass patterns, and laser polarization characteristics. The optimized setup was employed to characterize the laser power dependence for nitrogen, oxygen, and carbon dioxide detection. The results showed that the Raman scattering intensity varied linearly with the laser power of the gases, with linear fitting goodness R<sup>2</sup> values of 0.9902, 0.9848, and 0.9969, respectively. Finally, by configuring different concentrations of carbon dioxide gas using nitrogen, it was found that the Raman scattering intensity varied linearly with the concentration of carbon dioxide, with a linear fitting goodness R<sup>2</sup> of 0.9812. The system achieves a CO<sub>2</sub> detection limit of 500 ppm at 200 s integration time, meeting the requirements for greenhouse gas emission monitoring applications. |
| format | Article |
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| spelling | doaj-art-4cfc98df5f7445d0a0893cfd3d24b9db2025-06-25T13:21:35ZengMDPI AGAnalytica2673-45322025-04-01621310.3390/analytica6020013Characterization of Multi-Pass Enhanced Raman Spectroscopy for Gaseous MeasurementMiao Fan0Huinan Yang1Jun Chen2School of Energy and Power Engineering, University of Shanghai for Science and Technology, Shanghai 200093, ChinaSchool of Energy and Power Engineering, University of Shanghai for Science and Technology, Shanghai 200093, ChinaSchool of Energy and Power Engineering, University of Shanghai for Science and Technology, Shanghai 200093, ChinaWith the rise in global temperatures, it is of great significance to achieve rapid and accurate detection of greenhouse gases, such as carbon dioxide and methane. Raman spectroscopy not only overcomes the weakness of absorption spectroscopy in simultaneously measuring homonuclear diatomic molecules but also enables the simultaneous detection of multiple gases using a single-wavelength laser. However, due to the small Raman scattering cross-section and weak intensity of molecules, its application in gas detection is limited. To enhance the intensity of Raman scattering, this paper designs and constructs a multi-pass enhanced Raman spectroscopy setup. This study focuses on the effects of Raman scattering collection geometry, laser multi-pass patterns, and laser polarization relative to the Raman collection direction on signal intensity. Investigations into Raman scattering collection angles of 30°, 60°, and 90° reveal that the Raman scattering signal intensity increases as the collection angle decreases. Different laser multi-pass patterns also impact the signal, with the near-concentric linear multi-pass pattern found to collect more signals. To minimize the influence of excitation light on the signal, a side collection system is employed. Experiments show that the Raman scattering signal is stronger when the laser polarization is perpendicular to the collection direction. This study achieves overall system performance enhancement through coordinated optimization of multiple physical mechanisms, including Raman scattering collection geometry, laser multi-pass patterns, and laser polarization characteristics. The optimized setup was employed to characterize the laser power dependence for nitrogen, oxygen, and carbon dioxide detection. The results showed that the Raman scattering intensity varied linearly with the laser power of the gases, with linear fitting goodness R<sup>2</sup> values of 0.9902, 0.9848, and 0.9969, respectively. Finally, by configuring different concentrations of carbon dioxide gas using nitrogen, it was found that the Raman scattering intensity varied linearly with the concentration of carbon dioxide, with a linear fitting goodness R<sup>2</sup> of 0.9812. The system achieves a CO<sub>2</sub> detection limit of 500 ppm at 200 s integration time, meeting the requirements for greenhouse gas emission monitoring applications.https://www.mdpi.com/2673-4532/6/2/13Raman spectroscopygas detectionmulti-pass cavity |
| spellingShingle | Miao Fan Huinan Yang Jun Chen Characterization of Multi-Pass Enhanced Raman Spectroscopy for Gaseous Measurement Analytica Raman spectroscopy gas detection multi-pass cavity |
| title | Characterization of Multi-Pass Enhanced Raman Spectroscopy for Gaseous Measurement |
| title_full | Characterization of Multi-Pass Enhanced Raman Spectroscopy for Gaseous Measurement |
| title_fullStr | Characterization of Multi-Pass Enhanced Raman Spectroscopy for Gaseous Measurement |
| title_full_unstemmed | Characterization of Multi-Pass Enhanced Raman Spectroscopy for Gaseous Measurement |
| title_short | Characterization of Multi-Pass Enhanced Raman Spectroscopy for Gaseous Measurement |
| title_sort | characterization of multi pass enhanced raman spectroscopy for gaseous measurement |
| topic | Raman spectroscopy gas detection multi-pass cavity |
| url | https://www.mdpi.com/2673-4532/6/2/13 |
| work_keys_str_mv | AT miaofan characterizationofmultipassenhancedramanspectroscopyforgaseousmeasurement AT huinanyang characterizationofmultipassenhancedramanspectroscopyforgaseousmeasurement AT junchen characterizationofmultipassenhancedramanspectroscopyforgaseousmeasurement |