Catalyzed and Promoted Direct Reaction of Ethyl Chloride with Silicon Using Stirred-Bed Reactor
In this paper a stirred-bed performed of the copper catalyzed synthesis of ethylchlorosilanes from silicon and ethyl chloride was described. A Si-catalyst mixture prepared by reaction of CuCl and Si was employed. The compositions of products were mainly ethyltrichlorosilane, diethyldichlorosilane, a...
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| Format: | Article |
| Language: | English |
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University of Baghdad, College of Science for Women
2007-09-01
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| Series: | مجلة بغداد للعلوم |
| Online Access: | http://bsj.uobaghdad.edu.iq/index.php/BSJ/article/view/821 |
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| author | Baghdad Science Journal |
| author_facet | Baghdad Science Journal |
| author_sort | Baghdad Science Journal |
| collection | DOAJ |
| description | In this paper a stirred-bed performed of the copper catalyzed synthesis of ethylchlorosilanes from silicon and ethyl chloride was described. A Si-catalyst mixture prepared by reaction of CuCl and Si was employed. The compositions of products were mainly ethyltrichlorosilane, diethyldichlorosilane, and ethyldichlorosilane and mainly depended on the extent of Cu in the mixture and the reaction temperature. A promoting effect on the extent of adsorption was observed on the addition of certain additives. The kinetic data revealed the direct depended of the reaction rate on C2H5Cl pressure. |
| format | Article |
| id | doaj-art-276b3170d8c24d4c9e5ff0624c2025f7 |
| institution | Matheson Library |
| issn | 2078-8665 2411-7986 |
| language | English |
| publishDate | 2007-09-01 |
| publisher | University of Baghdad, College of Science for Women |
| record_format | Article |
| series | مجلة بغداد للعلوم |
| spelling | doaj-art-276b3170d8c24d4c9e5ff0624c2025f72025-08-02T03:46:13ZengUniversity of Baghdad, College of Science for Womenمجلة بغداد للعلوم2078-86652411-79862007-09-014310.21123/bsj.4.3.425-429Catalyzed and Promoted Direct Reaction of Ethyl Chloride with Silicon Using Stirred-Bed ReactorBaghdad Science JournalIn this paper a stirred-bed performed of the copper catalyzed synthesis of ethylchlorosilanes from silicon and ethyl chloride was described. A Si-catalyst mixture prepared by reaction of CuCl and Si was employed. The compositions of products were mainly ethyltrichlorosilane, diethyldichlorosilane, and ethyldichlorosilane and mainly depended on the extent of Cu in the mixture and the reaction temperature. A promoting effect on the extent of adsorption was observed on the addition of certain additives. The kinetic data revealed the direct depended of the reaction rate on C2H5Cl pressure.http://bsj.uobaghdad.edu.iq/index.php/BSJ/article/view/821 |
| spellingShingle | Baghdad Science Journal Catalyzed and Promoted Direct Reaction of Ethyl Chloride with Silicon Using Stirred-Bed Reactor مجلة بغداد للعلوم |
| title | Catalyzed and Promoted Direct Reaction of Ethyl Chloride with Silicon Using Stirred-Bed Reactor |
| title_full | Catalyzed and Promoted Direct Reaction of Ethyl Chloride with Silicon Using Stirred-Bed Reactor |
| title_fullStr | Catalyzed and Promoted Direct Reaction of Ethyl Chloride with Silicon Using Stirred-Bed Reactor |
| title_full_unstemmed | Catalyzed and Promoted Direct Reaction of Ethyl Chloride with Silicon Using Stirred-Bed Reactor |
| title_short | Catalyzed and Promoted Direct Reaction of Ethyl Chloride with Silicon Using Stirred-Bed Reactor |
| title_sort | catalyzed and promoted direct reaction of ethyl chloride with silicon using stirred bed reactor |
| url | http://bsj.uobaghdad.edu.iq/index.php/BSJ/article/view/821 |
| work_keys_str_mv | AT baghdadsciencejournal catalyzedandpromoteddirectreactionofethylchloridewithsiliconusingstirredbedreactor |