Side chain polysiloxanes with phthalocyanine moieties

Side chain polysiloxanes with phthalocyanine moieties

Side chain polysiloxane with 5-(pentyloxy)-3-methyloxy-9,10,16,17,23,24-hexakis(octenyloxy)phthalocyanine moieties is synthesized by hydrosilylation reaction. The phase behavior and thermooptical properties of the polysiloxane and starting 2-(pent-4-enyloxy)-3-methyloxy-9,10,16,17,23,24-hexakis(octe...

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Bibliographic Details
Main Authors: T. Ganicz, T. Makowski, W. A. Stanczyk, A. Tracz
Format: Article
Language:English
Published: Budapest University of Technology and Economics 2012-05-01
Series:eXPRESS Polymer Letters
Subjects:
Thermal properties
polysiloxanes
phthalocyanines
electro-optical properties
polymer synthesis
Online Access:http://www.expresspolymlett.com/letolt.php?file=EPL-0003022&mi=cd
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Summary:Side chain polysiloxane with 5-(pentyloxy)-3-methyloxy-9,10,16,17,23,24-hexakis(octenyloxy)phthalocyanine moieties is synthesized by hydrosilylation reaction. The phase behavior and thermooptical properties of the polysiloxane and starting 2-(pent-4-enyloxy)-3-methyloxy-9,10,16,17,23,24-hexakis(octenyloxy)phthalocyanine is examined by POM (Polarizing optical microscopy), TOA (thermooptical analysis), DSC (differential scanning calorimetry), AFM (atomic force microscopy) and SAXS (small angle X-ray scattering) studies. The effect of the attachment of phthalocyanine to polysiloxane chains over phase transitions and phase morphology is discussed in details.
ISSN:1788-618X

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