Development of a Highly Reliable PbS QDs-Based SWIR Photodetector Based on Metal Oxide Electron/Hole Extraction Layer Formation Conditions

Recently, with the development of automation technology in various fields, much research has been conducted on infrared photodetectors, which are the core technology of LiDAR sensors. However, most infrared photodetectors are expensive because they use compound semiconductors based on epitaxial proc...

Full description

Saved in:
Bibliographic Details
Main Authors: JinBeom Kwon, Yuntae Ha, Suji Choi, Donggeon Jung
Format: Article
Language:English
Published: MDPI AG 2025-07-01
Series:Nanomaterials
Subjects:
Online Access:https://www.mdpi.com/2079-4991/15/14/1107
Tags: Add Tag
No Tags, Be the first to tag this record!
_version_ 1839615444762230784
author JinBeom Kwon
Yuntae Ha
Suji Choi
Donggeon Jung
author_facet JinBeom Kwon
Yuntae Ha
Suji Choi
Donggeon Jung
author_sort JinBeom Kwon
collection DOAJ
description Recently, with the development of automation technology in various fields, much research has been conducted on infrared photodetectors, which are the core technology of LiDAR sensors. However, most infrared photodetectors are expensive because they use compound semiconductors based on epitaxial processes, and they have low safety because they use the near-infrared (NIR) region that can damage the retina. Therefore, they are difficult to apply to automation technologies such as automobiles and factories where humans can be constantly exposed. In contrast, short-wavelength infrared photodetectors based on PbS QDs are actively being developed because they can absorb infrared rays in the eye-safe region by controlling the particle size of QDs and can be easily and inexpensively manufactured through a solution process. However, PbS QDs-based SWIR photodetectors have low chemical stability due to the electron/hole extraction layer processed by the solution process, making it difficult to manufacture them in the form of patterning and arrays. In this study, bulk NiO and ZnO were deposited by sputtering to achieve uniformity and patterning of thin films, and the performance of PbS QDs-based photodetectors was improved by optimizing the thickness and annealing conditions of the thin films. The fabricated photodetector achieved a high response characteristic of 114.3% through optimized band gap and improved transmittance characteristics.
format Article
id doaj-art-2575b51de15c4d13bc055301672b8ca1
institution Matheson Library
issn 2079-4991
language English
publishDate 2025-07-01
publisher MDPI AG
record_format Article
series Nanomaterials
spelling doaj-art-2575b51de15c4d13bc055301672b8ca12025-07-25T13:32:21ZengMDPI AGNanomaterials2079-49912025-07-011514110710.3390/nano15141107Development of a Highly Reliable PbS QDs-Based SWIR Photodetector Based on Metal Oxide Electron/Hole Extraction Layer Formation ConditionsJinBeom Kwon0Yuntae Ha1Suji Choi2Donggeon Jung3Advanced Mobility System Group, Korea Institute of Industrial Technology (KITECH), Daegu 42994, Republic of KoreaAdvanced Mobility System Group, Korea Institute of Industrial Technology (KITECH), Daegu 42994, Republic of KoreaAdvanced Mobility System Group, Korea Institute of Industrial Technology (KITECH), Daegu 42994, Republic of KoreaAdvanced Mobility System Group, Korea Institute of Industrial Technology (KITECH), Daegu 42994, Republic of KoreaRecently, with the development of automation technology in various fields, much research has been conducted on infrared photodetectors, which are the core technology of LiDAR sensors. However, most infrared photodetectors are expensive because they use compound semiconductors based on epitaxial processes, and they have low safety because they use the near-infrared (NIR) region that can damage the retina. Therefore, they are difficult to apply to automation technologies such as automobiles and factories where humans can be constantly exposed. In contrast, short-wavelength infrared photodetectors based on PbS QDs are actively being developed because they can absorb infrared rays in the eye-safe region by controlling the particle size of QDs and can be easily and inexpensively manufactured through a solution process. However, PbS QDs-based SWIR photodetectors have low chemical stability due to the electron/hole extraction layer processed by the solution process, making it difficult to manufacture them in the form of patterning and arrays. In this study, bulk NiO and ZnO were deposited by sputtering to achieve uniformity and patterning of thin films, and the performance of PbS QDs-based photodetectors was improved by optimizing the thickness and annealing conditions of the thin films. The fabricated photodetector achieved a high response characteristic of 114.3% through optimized band gap and improved transmittance characteristics.https://www.mdpi.com/2079-4991/15/14/1107quantum dotsPbSSWIRLiDAR sensor
spellingShingle JinBeom Kwon
Yuntae Ha
Suji Choi
Donggeon Jung
Development of a Highly Reliable PbS QDs-Based SWIR Photodetector Based on Metal Oxide Electron/Hole Extraction Layer Formation Conditions
Nanomaterials
quantum dots
PbS
SWIR
LiDAR sensor
title Development of a Highly Reliable PbS QDs-Based SWIR Photodetector Based on Metal Oxide Electron/Hole Extraction Layer Formation Conditions
title_full Development of a Highly Reliable PbS QDs-Based SWIR Photodetector Based on Metal Oxide Electron/Hole Extraction Layer Formation Conditions
title_fullStr Development of a Highly Reliable PbS QDs-Based SWIR Photodetector Based on Metal Oxide Electron/Hole Extraction Layer Formation Conditions
title_full_unstemmed Development of a Highly Reliable PbS QDs-Based SWIR Photodetector Based on Metal Oxide Electron/Hole Extraction Layer Formation Conditions
title_short Development of a Highly Reliable PbS QDs-Based SWIR Photodetector Based on Metal Oxide Electron/Hole Extraction Layer Formation Conditions
title_sort development of a highly reliable pbs qds based swir photodetector based on metal oxide electron hole extraction layer formation conditions
topic quantum dots
PbS
SWIR
LiDAR sensor
url https://www.mdpi.com/2079-4991/15/14/1107
work_keys_str_mv AT jinbeomkwon developmentofahighlyreliablepbsqdsbasedswirphotodetectorbasedonmetaloxideelectronholeextractionlayerformationconditions
AT yuntaeha developmentofahighlyreliablepbsqdsbasedswirphotodetectorbasedonmetaloxideelectronholeextractionlayerformationconditions
AT sujichoi developmentofahighlyreliablepbsqdsbasedswirphotodetectorbasedonmetaloxideelectronholeextractionlayerformationconditions
AT donggeonjung developmentofahighlyreliablepbsqdsbasedswirphotodetectorbasedonmetaloxideelectronholeextractionlayerformationconditions