Novel azo-peresters radical initiators used for the synthesis of acrylic pressure-sensitive adhesives
Acrylic pressure-sensitive adhesives (PSA) based on two monomers: 2-ethylhexyl acrylate and acrylic acid were synthesized in organic solvent ethyl acetate using AIBN (2, 2'-azo-diisobutyronitrile) and new synthesized azo-peresters as radical initiators. After polymerization the visc...
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| Format: | Article |
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| Language: | English |
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Budapest University of Technology and Economics
2008-04-01
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| Series: | eXPRESS Polymer Letters |
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| Online Access: | http://www.expresspolymlett.com/letolt.php?file=EPL-0000588&mi=cd |
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| collection | DOAJ |
| description | Acrylic pressure-sensitive adhesives (PSA) based on two monomers: 2-ethylhexyl acrylate and acrylic acid were synthesized in organic solvent ethyl acetate using AIBN (2, 2'-azo-diisobutyronitrile) and new synthesized azo-peresters as radical initiators. After polymerization the viscosity, molecular weight and polydispersity of synthesized acrylic PSA were evaluated. The novel synthesized radical azo-perester initiators were synthesized, isolated and compared with industrial predominant usable azo-initiator AIBN. |
| format | Article |
| id | doaj-art-21f45b547ebb46ecb077d7779bb30bc9 |
| institution | Matheson Library |
| issn | 1788-618X |
| language | English |
| publishDate | 2008-04-01 |
| publisher | Budapest University of Technology and Economics |
| record_format | Article |
| series | eXPRESS Polymer Letters |
| spelling | doaj-art-21f45b547ebb46ecb077d7779bb30bc92025-07-02T03:59:07ZengBudapest University of Technology and EconomicseXPRESS Polymer Letters1788-618X2008-04-012427728310.3144/expresspolymlett.2008.33Novel azo-peresters radical initiators used for the synthesis of acrylic pressure-sensitive adhesivesAcrylic pressure-sensitive adhesives (PSA) based on two monomers: 2-ethylhexyl acrylate and acrylic acid were synthesized in organic solvent ethyl acetate using AIBN (2, 2'-azo-diisobutyronitrile) and new synthesized azo-peresters as radical initiators. After polymerization the viscosity, molecular weight and polydispersity of synthesized acrylic PSA were evaluated. The novel synthesized radical azo-perester initiators were synthesized, isolated and compared with industrial predominant usable azo-initiator AIBN.http://www.expresspolymlett.com/letolt.php?file=EPL-0000588&mi=cdPolymer synthesis, molecular eAIBNradical azo-perester initiatorsynthesis of acrylic PSAviscosity |
| spellingShingle | Novel azo-peresters radical initiators used for the synthesis of acrylic pressure-sensitive adhesives eXPRESS Polymer Letters Polymer synthesis, molecular e AIBN radical azo-perester initiator synthesis of acrylic PSA viscosity |
| title | Novel azo-peresters radical initiators used for the synthesis of acrylic pressure-sensitive adhesives |
| title_full | Novel azo-peresters radical initiators used for the synthesis of acrylic pressure-sensitive adhesives |
| title_fullStr | Novel azo-peresters radical initiators used for the synthesis of acrylic pressure-sensitive adhesives |
| title_full_unstemmed | Novel azo-peresters radical initiators used for the synthesis of acrylic pressure-sensitive adhesives |
| title_short | Novel azo-peresters radical initiators used for the synthesis of acrylic pressure-sensitive adhesives |
| title_sort | novel azo peresters radical initiators used for the synthesis of acrylic pressure sensitive adhesives |
| topic | Polymer synthesis, molecular e AIBN radical azo-perester initiator synthesis of acrylic PSA viscosity |
| url | http://www.expresspolymlett.com/letolt.php?file=EPL-0000588&mi=cd |