Desalination and Treatment of Oilfield Produced Waters

Produced water is a salty and organic-polluted byproduct drilled out during the oil extraction. An annual production of 11.2 million of m3 is estimated, based on the production of at least 3 barrels of PW for every barrel of oil extracted. The composition changes according to the well characteristic...

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Main Authors: Giovanni Campisi, Alice Sorrenti, Paulo B. Mofatto, Alessandro Cosenza, Serena Randazzo, Santo F. Corsino, Marco Capodici, Michele Torregrossa, Alessandro Tamburini, Giorgio Micale
Format: Article
Language:English
Published: AIDIC Servizi S.r.l. 2025-07-01
Series:Chemical Engineering Transactions
Online Access:https://www.cetjournal.it/index.php/cet/article/view/15331
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author Giovanni Campisi
Alice Sorrenti
Paulo B. Mofatto
Alessandro Cosenza
Serena Randazzo
Santo F. Corsino
Marco Capodici
Michele Torregrossa
Alessandro Tamburini
Giorgio Micale
author_facet Giovanni Campisi
Alice Sorrenti
Paulo B. Mofatto
Alessandro Cosenza
Serena Randazzo
Santo F. Corsino
Marco Capodici
Michele Torregrossa
Alessandro Tamburini
Giorgio Micale
author_sort Giovanni Campisi
collection DOAJ
description Produced water is a salty and organic-polluted byproduct drilled out during the oil extraction. An annual production of 11.2 million of m3 is estimated, based on the production of at least 3 barrels of PW for every barrel of oil extracted. The composition changes according to the well characteristics and to the addition of chemicals during the extraction process. Generally, a high salinity (up to 300 g L-1), due to the contact with subsurface rocks, is observed together with a large amount of dissolved hydrocarbon compound contaminants. Thus, their treatment could be designed on case-by-case basis through tailored studies and experimental investigations as it is not possible to standardize the characteristics of PW. In this work, an innovative PWs treatment scheme is proposed where an Assisted Reverse Electrodialysis (ARED) unit and a Sequencing Batch Moving Bed Biofilm Reactor (SBMBBR) were coupled: ARED is used to reduce the PWs salinity to values lower than 20 g L-1 of NaCl to let the stream compatible with the downstream biologic treatment, where the organic content is reduced ensuring compliance with legislative disposal limits. The desalination was performed under current-control mode and the ARED required less than 2 kWh·m-3PW for reaching the target outlet concentration. The organic content in SBMBBR successfully decreased, showing a Total Organic Carbon (TOC) abatement of about 80%.
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spelling doaj-art-13e2b975e34c48a39d33a12c6377ab8d2025-07-31T06:40:53ZengAIDIC Servizi S.r.l.Chemical Engineering Transactions2283-92162025-07-01117Desalination and Treatment of Oilfield Produced WatersGiovanni CampisiAlice SorrentiPaulo B. MofattoAlessandro CosenzaSerena RandazzoSanto F. CorsinoMarco CapodiciMichele TorregrossaAlessandro TamburiniGiorgio MicaleProduced water is a salty and organic-polluted byproduct drilled out during the oil extraction. An annual production of 11.2 million of m3 is estimated, based on the production of at least 3 barrels of PW for every barrel of oil extracted. The composition changes according to the well characteristics and to the addition of chemicals during the extraction process. Generally, a high salinity (up to 300 g L-1), due to the contact with subsurface rocks, is observed together with a large amount of dissolved hydrocarbon compound contaminants. Thus, their treatment could be designed on case-by-case basis through tailored studies and experimental investigations as it is not possible to standardize the characteristics of PW. In this work, an innovative PWs treatment scheme is proposed where an Assisted Reverse Electrodialysis (ARED) unit and a Sequencing Batch Moving Bed Biofilm Reactor (SBMBBR) were coupled: ARED is used to reduce the PWs salinity to values lower than 20 g L-1 of NaCl to let the stream compatible with the downstream biologic treatment, where the organic content is reduced ensuring compliance with legislative disposal limits. The desalination was performed under current-control mode and the ARED required less than 2 kWh·m-3PW for reaching the target outlet concentration. The organic content in SBMBBR successfully decreased, showing a Total Organic Carbon (TOC) abatement of about 80%.https://www.cetjournal.it/index.php/cet/article/view/15331
spellingShingle Giovanni Campisi
Alice Sorrenti
Paulo B. Mofatto
Alessandro Cosenza
Serena Randazzo
Santo F. Corsino
Marco Capodici
Michele Torregrossa
Alessandro Tamburini
Giorgio Micale
Desalination and Treatment of Oilfield Produced Waters
Chemical Engineering Transactions
title Desalination and Treatment of Oilfield Produced Waters
title_full Desalination and Treatment of Oilfield Produced Waters
title_fullStr Desalination and Treatment of Oilfield Produced Waters
title_full_unstemmed Desalination and Treatment of Oilfield Produced Waters
title_short Desalination and Treatment of Oilfield Produced Waters
title_sort desalination and treatment of oilfield produced waters
url https://www.cetjournal.it/index.php/cet/article/view/15331
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