Triazine Calixarene as a Dual-Channel Chemosensor for the Reversible Detection of Cu<sup>2+</sup> and I<sup>−</sup> Ions via Water Content Modulation
Rationally designing and synthesizing chemosensors capable of simultaneously detecting both anions and cations via water content modulation is challenging. In this study, we synthesized and characterized a novel triazine calixarene derivative-based iodide and copper ion-selective fluorescent “turn-o...
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| Main Authors: | , , , , , , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
MDPI AG
2025-06-01
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| Series: | Molecules |
| Subjects: | |
| Online Access: | https://www.mdpi.com/1420-3049/30/13/2815 |
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| Summary: | Rationally designing and synthesizing chemosensors capable of simultaneously detecting both anions and cations via water content modulation is challenging. In this study, we synthesized and characterized a novel triazine calixarene derivative-based iodide and copper ion-selective fluorescent “turn-off” sensor. This dual-channeled fluorescent probe is able to recognize Cu<sup>2+</sup> and I<sup>−</sup> ions simultaneously in aqueous systems. The fluorescent sensor <b>s4</b> was synthesized by displacement reaction of acridine with 1, 3-bis (dichloro-mono-triazinoxy) benzene in acetonitrile. Mass spectrometry (MS), UV-vis, and fluorescence spectra were acquired to characterize the fluorescence response of <b>s4</b> to different cations and anions, while infrared (IR) spectroscopy and isothermal titration calorimetry (ITC) were employed to study the underlying selectivity mechanism of <b>s4</b> to Cu<sup>2+</sup> and I<sup>−</sup>. In detail, <b>s4</b> displayed extremely high sensitivity to Cu<sup>2+</sup> with over 80% fluorescence decrement caused by the paramagnetic nature of Cu<sup>2+</sup> in the aqueous media. The reversible fluorescence response to Cu<sup>2+</sup> and the responses to Cu<sup>2+</sup> in the solution of other potential interferent cations, such as Li<sup>+</sup>, Na<sup>+</sup>, K<sup>+</sup>, Ca<sup>2+</sup>, Cd<sup>2+</sup>, Zn<sup>2+</sup>, Sr<sup>2+</sup>, Ni<sup>2+</sup>, Co<sup>2+</sup> were also investigated. Probe <b>s4</b> also exhibited very good fluorescence selectivity to iodide ions under various anion (F<sup>−</sup>, Cl<sup>−</sup>, Br<sup>−</sup>, NO<sub>3</sub><sup>−</sup>, HSO<sub>4</sub><sup>−</sup>, ClO<sub>4</sub><sup>−</sup>, PF<sub>6</sub><sup>−</sup>, AcO<sup>−</sup>, H<sub>2</sub>PO<sub>4</sub><sup>−</sup>) interferences. In addition to the fluorescent response to I<sup>−</sup>, <b>s4</b> showed a highly selective naked-eye-detectable color change from colorless to yellow with the other tested anions. |
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| ISSN: | 1420-3049 |