Synthesis and characterization of polypyrrole doped with anionic spherical polyelectrolyte brushes

The procedures for the synthesis of polypyrrole (PPy) doped with anionic spherical polyelectrolyte brushes (ASPB) (PPy/ASPB nanocomposite) by means of in situ chemical oxidative polymerization were presented. Fourier transform infrared spectroscopy (FTIR) and Raman spectroscopic analysis suggested t...

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Main Authors: N. Su, H. B. Li, S. J. Yuan, S. P. Yi, E. Q. Yin
Format: Article
Language:English
Published: Budapest University of Technology and Economics 2012-09-01
Series:eXPRESS Polymer Letters
Subjects:
Online Access:http://www.expresspolymlett.com/letolt.php?file=EPL-0003325&mi=cd
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author N. Su
H. B. Li
S. J. Yuan
S. P. Yi
E. Q. Yin
author_facet N. Su
H. B. Li
S. J. Yuan
S. P. Yi
E. Q. Yin
author_sort N. Su
collection DOAJ
description The procedures for the synthesis of polypyrrole (PPy) doped with anionic spherical polyelectrolyte brushes (ASPB) (PPy/ASPB nanocomposite) by means of in situ chemical oxidative polymerization were presented. Fourier transform infrared spectroscopy (FTIR) and Raman spectroscopic analysis suggested the bonding structure of PPy/ASPB nanocomposite. Scanning electron microscopy (SEM) was used to confirm the morphologies of samples. The crystallographic structure, chemical nature and thermal stability of conducting polymers were analyzed by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and Thermo-gravimetric analysis (TGA) respectively. Investigation of the electrical conductivity at room temperature showed that the electrical conductivity of PPy/ASPB nanocomposite was 20 S/cm, which was higher than that of PPy (3.6 S/cm).
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publishDate 2012-09-01
publisher Budapest University of Technology and Economics
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series eXPRESS Polymer Letters
spelling doaj-art-0ed2e941a4af4cadb9931f922e7d6c7c2025-07-02T01:49:43ZengBudapest University of Technology and EconomicseXPRESS Polymer Letters1788-618X2012-09-016969770510.3144/expresspolymlett.2012.75Synthesis and characterization of polypyrrole doped with anionic spherical polyelectrolyte brushesN. SuH. B. LiS. J. YuanS. P. YiE. Q. YinThe procedures for the synthesis of polypyrrole (PPy) doped with anionic spherical polyelectrolyte brushes (ASPB) (PPy/ASPB nanocomposite) by means of in situ chemical oxidative polymerization were presented. Fourier transform infrared spectroscopy (FTIR) and Raman spectroscopic analysis suggested the bonding structure of PPy/ASPB nanocomposite. Scanning electron microscopy (SEM) was used to confirm the morphologies of samples. The crystallographic structure, chemical nature and thermal stability of conducting polymers were analyzed by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and Thermo-gravimetric analysis (TGA) respectively. Investigation of the electrical conductivity at room temperature showed that the electrical conductivity of PPy/ASPB nanocomposite was 20 S/cm, which was higher than that of PPy (3.6 S/cm).http://www.expresspolymlett.com/letolt.php?file=EPL-0003325&mi=cdNanocompositesconducting polymersanionic spherical polyelectroldopingelectrical conductivity
spellingShingle N. Su
H. B. Li
S. J. Yuan
S. P. Yi
E. Q. Yin
Synthesis and characterization of polypyrrole doped with anionic spherical polyelectrolyte brushes
eXPRESS Polymer Letters
Nanocomposites
conducting polymers
anionic spherical polyelectrol
doping
electrical conductivity
title Synthesis and characterization of polypyrrole doped with anionic spherical polyelectrolyte brushes
title_full Synthesis and characterization of polypyrrole doped with anionic spherical polyelectrolyte brushes
title_fullStr Synthesis and characterization of polypyrrole doped with anionic spherical polyelectrolyte brushes
title_full_unstemmed Synthesis and characterization of polypyrrole doped with anionic spherical polyelectrolyte brushes
title_short Synthesis and characterization of polypyrrole doped with anionic spherical polyelectrolyte brushes
title_sort synthesis and characterization of polypyrrole doped with anionic spherical polyelectrolyte brushes
topic Nanocomposites
conducting polymers
anionic spherical polyelectrol
doping
electrical conductivity
url http://www.expresspolymlett.com/letolt.php?file=EPL-0003325&mi=cd
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AT sjyuan synthesisandcharacterizationofpolypyrroledopedwithanionicsphericalpolyelectrolytebrushes
AT spyi synthesisandcharacterizationofpolypyrroledopedwithanionicsphericalpolyelectrolytebrushes
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