The preparation of 1-(β-naphthyl)-3-ferrocenylpyrazole-4-carbaldehyde and syntheses on the base of it

Synthesis of 1-(β-naphthyl)-3-ferrocenyl pyrazole-4-carbaldehyde was carried out from acetylferrocene and naphthalen-2-ylhydrazine followed by intramolecular cyclization under Vilsmeier-Haack conditions. The reaction of reductive amination of aldehydes obtained with primary and secondary amines incl...

Full description

Saved in:
Bibliographic Details
Main Authors: E. Yu. Osipova, A. A. Simenel, A. N. Rodionov, V. V. Kachala, K. Ya. Zherebker
Format: Article
Language:Russian
Published: MIREA - Russian Technological University 2009-04-01
Series:Тонкие химические технологии
Subjects:
Online Access:https://www.finechem-mirea.ru/jour/article/view/1113
Tags: Add Tag
No Tags, Be the first to tag this record!
_version_ 1839581423707619328
author E. Yu. Osipova
A. A. Simenel
A. N. Rodionov
V. V. Kachala
K. Ya. Zherebker
author_facet E. Yu. Osipova
A. A. Simenel
A. N. Rodionov
V. V. Kachala
K. Ya. Zherebker
author_sort E. Yu. Osipova
collection DOAJ
description Synthesis of 1-(β-naphthyl)-3-ferrocenyl pyrazole-4-carbaldehyde was carried out from acetylferrocene and naphthalen-2-ylhydrazine followed by intramolecular cyclization under Vilsmeier-Haack conditions. The reaction of reductive amination of aldehydes obtained with primary and secondary amines including methyl esters of amino acids was studied.
format Article
id doaj-art-059db467a33d4b659efde0cea9c8df24
institution Matheson Library
issn 2410-6593
2686-7575
language Russian
publishDate 2009-04-01
publisher MIREA - Russian Technological University
record_format Article
series Тонкие химические технологии
spelling doaj-art-059db467a33d4b659efde0cea9c8df242025-08-04T10:19:32ZrusMIREA - Russian Technological UniversityТонкие химические технологии2410-65932686-75752009-04-01421001051107The preparation of 1-(β-naphthyl)-3-ferrocenylpyrazole-4-carbaldehyde and syntheses on the base of itE. Yu. Osipova0A. A. Simenel1A. N. Rodionov2V. V. Kachala3K. Ya. Zherebker4МИТХТ им. М.В. Ломоносова, 119571, Москва, пр-т Вернадского, д. 86Институт элементоорганических соединений им. А.Н. Несмеянова РАНИнститут элементоорганических соединений им. А.Н. Несмеянова РАНИнститут органической химии им. Н.Д. Зелинского РАНМИТХТ им. М.В. Ломоносова, 119571, Москва, пр-т Вернадского, д. 86Synthesis of 1-(β-naphthyl)-3-ferrocenyl pyrazole-4-carbaldehyde was carried out from acetylferrocene and naphthalen-2-ylhydrazine followed by intramolecular cyclization under Vilsmeier-Haack conditions. The reaction of reductive amination of aldehydes obtained with primary and secondary amines including methyl esters of amino acids was studied.https://www.finechem-mirea.ru/jour/article/view/1113acetylferrocenevilsmeier-haack reagentpyrazolesreductive aminationtriacetoxiborhydride
spellingShingle E. Yu. Osipova
A. A. Simenel
A. N. Rodionov
V. V. Kachala
K. Ya. Zherebker
The preparation of 1-(β-naphthyl)-3-ferrocenylpyrazole-4-carbaldehyde and syntheses on the base of it
Тонкие химические технологии
acetylferrocene
vilsmeier-haack reagent
pyrazoles
reductive amination
triacetoxiborhydride
title The preparation of 1-(β-naphthyl)-3-ferrocenylpyrazole-4-carbaldehyde and syntheses on the base of it
title_full The preparation of 1-(β-naphthyl)-3-ferrocenylpyrazole-4-carbaldehyde and syntheses on the base of it
title_fullStr The preparation of 1-(β-naphthyl)-3-ferrocenylpyrazole-4-carbaldehyde and syntheses on the base of it
title_full_unstemmed The preparation of 1-(β-naphthyl)-3-ferrocenylpyrazole-4-carbaldehyde and syntheses on the base of it
title_short The preparation of 1-(β-naphthyl)-3-ferrocenylpyrazole-4-carbaldehyde and syntheses on the base of it
title_sort preparation of 1 β naphthyl 3 ferrocenylpyrazole 4 carbaldehyde and syntheses on the base of it
topic acetylferrocene
vilsmeier-haack reagent
pyrazoles
reductive amination
triacetoxiborhydride
url https://www.finechem-mirea.ru/jour/article/view/1113
work_keys_str_mv AT eyuosipova thepreparationof1bnaphthyl3ferrocenylpyrazole4carbaldehydeandsynthesesonthebaseofit
AT aasimenel thepreparationof1bnaphthyl3ferrocenylpyrazole4carbaldehydeandsynthesesonthebaseofit
AT anrodionov thepreparationof1bnaphthyl3ferrocenylpyrazole4carbaldehydeandsynthesesonthebaseofit
AT vvkachala thepreparationof1bnaphthyl3ferrocenylpyrazole4carbaldehydeandsynthesesonthebaseofit
AT kyazherebker thepreparationof1bnaphthyl3ferrocenylpyrazole4carbaldehydeandsynthesesonthebaseofit
AT eyuosipova preparationof1bnaphthyl3ferrocenylpyrazole4carbaldehydeandsynthesesonthebaseofit
AT aasimenel preparationof1bnaphthyl3ferrocenylpyrazole4carbaldehydeandsynthesesonthebaseofit
AT anrodionov preparationof1bnaphthyl3ferrocenylpyrazole4carbaldehydeandsynthesesonthebaseofit
AT vvkachala preparationof1bnaphthyl3ferrocenylpyrazole4carbaldehydeandsynthesesonthebaseofit
AT kyazherebker preparationof1bnaphthyl3ferrocenylpyrazole4carbaldehydeandsynthesesonthebaseofit