The preparation of 1-(β-naphthyl)-3-ferrocenylpyrazole-4-carbaldehyde and syntheses on the base of it
Synthesis of 1-(β-naphthyl)-3-ferrocenyl pyrazole-4-carbaldehyde was carried out from acetylferrocene and naphthalen-2-ylhydrazine followed by intramolecular cyclization under Vilsmeier-Haack conditions. The reaction of reductive amination of aldehydes obtained with primary and secondary amines incl...
Saved in:
Main Authors: | , , , , |
---|---|
Format: | Article |
Language: | Russian |
Published: |
MIREA - Russian Technological University
2009-04-01
|
Series: | Тонкие химические технологии |
Subjects: | |
Online Access: | https://www.finechem-mirea.ru/jour/article/view/1113 |
Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
_version_ | 1839581423707619328 |
---|---|
author | E. Yu. Osipova A. A. Simenel A. N. Rodionov V. V. Kachala K. Ya. Zherebker |
author_facet | E. Yu. Osipova A. A. Simenel A. N. Rodionov V. V. Kachala K. Ya. Zherebker |
author_sort | E. Yu. Osipova |
collection | DOAJ |
description | Synthesis of 1-(β-naphthyl)-3-ferrocenyl pyrazole-4-carbaldehyde was carried out from acetylferrocene and naphthalen-2-ylhydrazine followed by intramolecular cyclization under Vilsmeier-Haack conditions. The reaction of reductive amination of aldehydes obtained with primary and secondary amines including methyl esters of amino acids was studied. |
format | Article |
id | doaj-art-059db467a33d4b659efde0cea9c8df24 |
institution | Matheson Library |
issn | 2410-6593 2686-7575 |
language | Russian |
publishDate | 2009-04-01 |
publisher | MIREA - Russian Technological University |
record_format | Article |
series | Тонкие химические технологии |
spelling | doaj-art-059db467a33d4b659efde0cea9c8df242025-08-04T10:19:32ZrusMIREA - Russian Technological UniversityТонкие химические технологии2410-65932686-75752009-04-01421001051107The preparation of 1-(β-naphthyl)-3-ferrocenylpyrazole-4-carbaldehyde and syntheses on the base of itE. Yu. Osipova0A. A. Simenel1A. N. Rodionov2V. V. Kachala3K. Ya. Zherebker4МИТХТ им. М.В. Ломоносова, 119571, Москва, пр-т Вернадского, д. 86Институт элементоорганических соединений им. А.Н. Несмеянова РАНИнститут элементоорганических соединений им. А.Н. Несмеянова РАНИнститут органической химии им. Н.Д. Зелинского РАНМИТХТ им. М.В. Ломоносова, 119571, Москва, пр-т Вернадского, д. 86Synthesis of 1-(β-naphthyl)-3-ferrocenyl pyrazole-4-carbaldehyde was carried out from acetylferrocene and naphthalen-2-ylhydrazine followed by intramolecular cyclization under Vilsmeier-Haack conditions. The reaction of reductive amination of aldehydes obtained with primary and secondary amines including methyl esters of amino acids was studied.https://www.finechem-mirea.ru/jour/article/view/1113acetylferrocenevilsmeier-haack reagentpyrazolesreductive aminationtriacetoxiborhydride |
spellingShingle | E. Yu. Osipova A. A. Simenel A. N. Rodionov V. V. Kachala K. Ya. Zherebker The preparation of 1-(β-naphthyl)-3-ferrocenylpyrazole-4-carbaldehyde and syntheses on the base of it Тонкие химические технологии acetylferrocene vilsmeier-haack reagent pyrazoles reductive amination triacetoxiborhydride |
title | The preparation of 1-(β-naphthyl)-3-ferrocenylpyrazole-4-carbaldehyde and syntheses on the base of it |
title_full | The preparation of 1-(β-naphthyl)-3-ferrocenylpyrazole-4-carbaldehyde and syntheses on the base of it |
title_fullStr | The preparation of 1-(β-naphthyl)-3-ferrocenylpyrazole-4-carbaldehyde and syntheses on the base of it |
title_full_unstemmed | The preparation of 1-(β-naphthyl)-3-ferrocenylpyrazole-4-carbaldehyde and syntheses on the base of it |
title_short | The preparation of 1-(β-naphthyl)-3-ferrocenylpyrazole-4-carbaldehyde and syntheses on the base of it |
title_sort | preparation of 1 β naphthyl 3 ferrocenylpyrazole 4 carbaldehyde and syntheses on the base of it |
topic | acetylferrocene vilsmeier-haack reagent pyrazoles reductive amination triacetoxiborhydride |
url | https://www.finechem-mirea.ru/jour/article/view/1113 |
work_keys_str_mv | AT eyuosipova thepreparationof1bnaphthyl3ferrocenylpyrazole4carbaldehydeandsynthesesonthebaseofit AT aasimenel thepreparationof1bnaphthyl3ferrocenylpyrazole4carbaldehydeandsynthesesonthebaseofit AT anrodionov thepreparationof1bnaphthyl3ferrocenylpyrazole4carbaldehydeandsynthesesonthebaseofit AT vvkachala thepreparationof1bnaphthyl3ferrocenylpyrazole4carbaldehydeandsynthesesonthebaseofit AT kyazherebker thepreparationof1bnaphthyl3ferrocenylpyrazole4carbaldehydeandsynthesesonthebaseofit AT eyuosipova preparationof1bnaphthyl3ferrocenylpyrazole4carbaldehydeandsynthesesonthebaseofit AT aasimenel preparationof1bnaphthyl3ferrocenylpyrazole4carbaldehydeandsynthesesonthebaseofit AT anrodionov preparationof1bnaphthyl3ferrocenylpyrazole4carbaldehydeandsynthesesonthebaseofit AT vvkachala preparationof1bnaphthyl3ferrocenylpyrazole4carbaldehydeandsynthesesonthebaseofit AT kyazherebker preparationof1bnaphthyl3ferrocenylpyrazole4carbaldehydeandsynthesesonthebaseofit |